Hexacyclo[11.10.1.02,7.09,24.014,23.017,22]tetracosa-1(24),2,4,6,8,10,12,14(23),15,17,19,21-dodecaene (C24H14) - excitons of #1646

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.103 2.964 eV
S2 0.236 3.450 eV
S3 0.055 3.984 eV
S4 0.031 4.198 eV
S5 0.239 4.588 eV
S6 0.107 4.677 eV
S7 0.244 4.986 eV
S8 0.064 5.091 eV
S9 0.016 5.258 eV
S10 0.124 5.349 eV
S11 0.002 5.433 eV
S12 0.183 5.582 eV
S13 0.852 5.696 eV
S14 0.092 5.874 eV
S15 0.115 5.985 eV
S16 0.057 6.109 eV
S17 0.019 6.129 eV
S18 0.064 6.164 eV
S19 0.703 6.212 eV
S20 0.203 6.301 eV
S21 0.139 6.402 eV
S22 1.342 6.464 eV
S23 0.026 6.528 eV
S24 0.306 6.572 eV
S25 0.108 6.648 eV
S26 0.129 6.708 eV
S27 0.056 6.717 eV
S28 0.077 6.747 eV
S29 0.092 6.804 eV
S30 0.008 6.838 eV
S31 0.013 6.936 eV
S32 0.022 6.938 eV
S33 0.029 6.972 eV
S34 0.023 6.994 eV
S35 0.012 7.037 eV
S36 0.426 7.118 eV
S37 0.003 7.196 eV
S38 0.051 7.222 eV
S39 0.006 7.290 eV
S40 0.014 7.299 eV
S41 0.083 7.398 eV
S42 0.010 7.409 eV
S43 0.106 7.437 eV
S44 0.044 7.465 eV
S45 0.011 7.497 eV
S46 0.010 7.522 eV
S47 0.023 7.549 eV
S48 0.002 7.581 eV
S49 0.072 7.630 eV
S50 0.045 7.649 eV
S51 0.009 7.655 eV
S52 0.032 7.688 eV
S53 0.119 7.699 eV
S54 0.038 7.725 eV
S55 0.013 7.755 eV
S56 0.030 7.787 eV
S57 0.007 7.816 eV
S58 0.088 7.876 eV
S59 0.072 7.886 eV
S60 0.015 7.911 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25102.77

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:14:18

Legacy ID None

System


Full Name Hexacyclo[11.10.1.02,7.09,24.014,23.017,22]tetracosa-1(24),2,4,6,8,10,12,14(23),15,17,19,21-dodecaene

Short Name dibenzo(a,l)fluoranthene

Formula C24H14

Mass 302.4 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1646 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM