Hexacyclo[11.10.1.03,8.09,24.014,23.016,21]tetracosa-1,3,5,7,9(24),10,12,14,16,18,20,22-dodecaene (C24H14) - excitons of #1653

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.300 3.867 eV
S2 A' 0.004 4.035 eV
S3 A' 0.085 4.240 eV
S4 A' 0.285 4.515 eV
S5 A' 0.359 4.603 eV
S6 A' 0.732 4.977 eV
S7 A' 0.314 5.222 eV
S8 A' 0.350 5.347 eV
S9 A' 0.761 5.370 eV
S10 A' 0.371 5.491 eV
S11 A' 0.008 5.683 eV
S12 A' 0.547 5.880 eV
S13 A' 0.197 5.984 eV
S14 A' 0.489 6.023 eV
S15 A' 0.026 6.210 eV
S16 A' 0.191 6.249 eV
S17 A' 0.129 6.374 eV
S18 A' 0.029 6.424 eV
S19 A' 0.052 6.551 eV
S20 A' 0.022 6.614 eV
S21 A" 0.000 6.620 eV
S22 A' 0.344 6.724 eV
S23 A' 0.122 6.758 eV
S24 A" 0.000 6.794 eV
S25 A' 0.158 6.835 eV
S26 A' 0.010 6.867 eV
S27 A" 0.000 6.878 eV
S28 A" 0.000 6.914 eV
S29 A" 0.000 7.006 eV
S30 A' 0.010 7.032 eV
S31 A' 0.092 7.043 eV
S32 A" 0.000 7.111 eV
S33 A' 0.023 7.156 eV
S34 A" 0.001 7.166 eV
S35 A" 0.000 7.278 eV
S36 A' 0.007 7.306 eV
S37 A" 0.001 7.330 eV
S38 A' 0.066 7.337 eV
S39 A" 0.001 7.339 eV
S40 A" 0.002 7.362 eV
S41 A' 0.030 7.403 eV
S42 A" 0.001 7.413 eV
S43 A' 0.070 7.479 eV
S44 A' 0.091 7.583 eV
S45 A" 0.000 7.584 eV
S46 A" 0.000 7.593 eV
S47 A' 0.126 7.651 eV
S48 A" 0.000 7.703 eV
S49 A" 0.003 7.714 eV
S50 A' 0.112 7.755 eV
S51 A" 0.001 7.763 eV
S52 A" 0.001 7.808 eV
S53 A" 0.004 7.818 eV
S54 A' 0.071 7.818 eV
S55 A" 0.002 7.854 eV
S56 A' 0.033 7.891 eV
S57 A' 0.121 7.951 eV
S58 A" 0.000 7.958 eV
S59 A" 0.000 7.988 eV
S60 A' 0.271 8.028 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25103.40

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:16:25

Legacy ID None

System


Full Name Hexacyclo[11.10.1.03,8.09,24.014,23.016,21]tetracosa-1,3,5,7,9(24),10,12,14,16,18,20,22-dodecaene

Short Name dibenzo(b,k)fluoranthene

Formula C24H14

Mass 302.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1653 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM