Hexacyclo[11.10.1.03,8.09,24.014,23.017,22]tetracosa-1,3,5,7,9(24),10,12,14(23),15,17,19,21-dodecaene (C24H14) - excitons of #1654

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.052 3.533 eV
S2 A' 0.262 3.933 eV
S3 A' 0.066 4.104 eV
S4 A' 0.434 4.469 eV
S5 A' 0.195 4.828 eV
S6 A' 0.007 4.997 eV
S7 A' 0.332 5.148 eV
S8 A' 0.092 5.273 eV
S9 A' 0.535 5.427 eV
S10 A' 0.376 5.511 eV
S11 A' 0.074 5.748 eV
S12 A' 0.588 5.788 eV
S13 A' 0.023 5.869 eV
S14 A' 0.118 6.091 eV
S15 A' 0.198 6.141 eV
S16 A' 0.078 6.208 eV
S17 A" 0.000 6.258 eV
S18 A' 0.012 6.306 eV
S19 A' 0.208 6.383 eV
S20 A' 0.597 6.485 eV
S21 A' 0.069 6.545 eV
S22 A" 0.000 6.570 eV
S23 A' 0.338 6.614 eV
S24 A' 0.219 6.681 eV
S25 A' 0.156 6.767 eV
S26 A' 0.507 6.870 eV
S27 A" 0.000 6.931 eV
S28 A" 0.000 6.941 eV
S29 A" 0.000 6.989 eV
S30 A' 0.142 7.049 eV
S31 A' 0.040 7.068 eV
S32 A" 0.000 7.094 eV
S33 A' 0.074 7.251 eV
S34 A" 0.000 7.253 eV
S35 A" 0.000 7.293 eV
S36 A' 0.095 7.307 eV
S37 A" 0.001 7.364 eV
S38 A" 0.001 7.401 eV
S39 A' 0.482 7.412 eV
S40 A" 0.000 7.476 eV
S41 A' 0.054 7.506 eV
S42 A' 0.092 7.517 eV
S43 A" 0.000 7.530 eV
S44 A' 0.049 7.541 eV
S45 A" 0.007 7.590 eV
S46 A' 0.104 7.599 eV
S47 A' 0.026 7.625 eV
S48 A" 0.001 7.649 eV
S49 A" 0.002 7.676 eV
S50 A" 0.000 7.694 eV
S51 A" 0.000 7.707 eV
S52 A" 0.003 7.752 eV
S53 A' 0.178 7.759 eV
S54 A' 0.050 7.794 eV
S55 A" 0.000 7.802 eV
S56 A' 0.059 7.886 eV
S57 A" 0.000 7.900 eV
S58 A' 0.000 7.923 eV
S59 A" 0.002 7.942 eV
S60 A' 0.037 7.979 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25103.34

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:16:43

Legacy ID None

System


Full Name Hexacyclo[11.10.1.03,8.09,24.014,23.017,22]tetracosa-1,3,5,7,9(24),10,12,14(23),15,17,19,21-dodecaene

Short Name dibenzo[b,l]fluoranthene

Formula C24H14

Mass 302.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1654 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM