Hexacyclo[16.3.1.02,7.08,21.011,20.014,19]docosa-1(22),2,4,6,8(21),9,11(20),12,14(19),15,17-undecaene (C22H12) - excitons of #1690

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.158 3.490 eV
S2 A' 0.133 3.897 eV
S3 A' 0.202 4.038 eV
S4 A' 0.159 4.620 eV
S5 A' 0.082 4.860 eV
S6 A' 0.370 5.041 eV
S7 A' 0.140 5.086 eV
S8 A' 0.138 5.407 eV
S9 A' 0.153 5.513 eV
S10 A' 0.101 5.692 eV
S11 A' 1.027 5.779 eV
S12 A' 0.659 5.893 eV
S13 A' 0.194 6.031 eV
S14 A" 0.000 6.195 eV
S15 A' 0.051 6.250 eV
S16 A' 0.011 6.276 eV
S17 A' 0.002 6.339 eV
S18 A' 0.272 6.435 eV
S19 A" 0.000 6.453 eV
S20 A' 0.060 6.554 eV
S21 A' 0.215 6.739 eV
S22 A' 0.341 6.819 eV
S23 A' 0.052 6.842 eV
S24 A" 0.000 6.909 eV
S25 A" 0.000 6.952 eV
S26 A' 0.347 6.994 eV
S27 A" 0.000 7.061 eV
S28 A' 0.300 7.127 eV
S29 A" 0.001 7.151 eV
S30 A" 0.000 7.166 eV
S31 A' 0.107 7.232 eV
S32 A' 0.465 7.267 eV
S33 A" 0.000 7.297 eV
S34 A" 0.002 7.381 eV
S35 A' 0.153 7.415 eV
S36 A" 0.000 7.445 eV
S37 A' 0.006 7.479 eV
S38 A" 0.002 7.489 eV
S39 A" 0.001 7.557 eV
S40 A' 0.285 7.582 eV
S41 A" 0.000 7.607 eV
S42 A" 0.000 7.625 eV
S43 A' 0.170 7.643 eV
S44 A" 0.001 7.762 eV
S45 A" 0.001 7.783 eV
S46 A" 0.005 7.840 eV
S47 A' 0.440 7.845 eV
S48 A" 0.002 7.872 eV
S49 A' 0.158 7.889 eV
S50 A" 0.001 7.899 eV
S51 A' 0.082 7.900 eV
S52 A" 0.001 7.908 eV
S53 A" 0.000 7.940 eV
S54 A" 0.003 7.973 eV
S55 A' 0.071 7.986 eV
S56 A' 0.085 8.011 eV
S57 A" 0.000 8.112 eV
S58 A' 0.012 8.125 eV
S59 A" 0.000 8.130 eV
S60 A' 0.127 8.151 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -22997.20

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:25:46

Legacy ID None

System


Full Name Hexacyclo[16.3.1.02,7.08,21.011,20.014,19]docosa-1(22),2,4,6,8(21),9,11(20),12,14(19),15,17-undecaene

Short Name indeno(1,2,3-cd)pyrene

Formula C22H12

Mass 276.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1690 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM