Hexacyclo[12.8.0.02,11.03,8.04,22.015,20]docosa-1(14),2(11),3(8),4,6,9,12,15,17,19,21-undecaene (C22H12) - excitons of #1694

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.059 3.761 eV
S2 A' 0.131 4.091 eV
S3 A' 0.051 4.234 eV
S4 A' 0.010 4.593 eV
S5 A' 0.301 4.758 eV
S6 A' 0.124 4.861 eV
S7 A' 0.332 5.269 eV
S8 A' 0.952 5.349 eV
S9 A' 0.037 5.413 eV
S10 A' 0.234 5.678 eV
S11 A' 0.188 5.835 eV
S12 A' 0.980 5.934 eV
S13 A' 0.450 6.077 eV
S14 A' 0.074 6.243 eV
S15 A' 0.218 6.384 eV
S16 A' 0.094 6.447 eV
S17 A" 0.000 6.447 eV
S18 A' 0.019 6.582 eV
S19 A' 0.035 6.660 eV
S20 A' 0.040 6.691 eV
S21 A" 0.000 6.696 eV
S22 A' 0.065 6.772 eV
S23 A' 0.068 6.831 eV
S24 A" 0.000 6.902 eV
S25 A' 0.897 6.943 eV
S26 A' 0.064 7.062 eV
S27 A" 0.000 7.083 eV
S28 A' 0.037 7.113 eV
S29 A" 0.000 7.176 eV
S30 A" 0.000 7.218 eV
S31 A' 0.047 7.236 eV
S32 A" 0.001 7.264 eV
S33 A' 0.094 7.320 eV
S34 A" 0.000 7.323 eV
S35 A" 0.001 7.356 eV
S36 A" 0.001 7.428 eV
S37 A' 0.221 7.472 eV
S38 A" 0.000 7.528 eV
S39 A" 0.012 7.550 eV
S40 A' 0.160 7.558 eV
S41 A" 0.000 7.598 eV
S42 A' 0.025 7.628 eV
S43 A" 0.000 7.684 eV
S44 A" 0.000 7.710 eV
S45 A' 0.164 7.726 eV
S46 A" 0.000 7.739 eV
S47 A" 0.000 7.774 eV
S48 A' 0.243 7.777 eV
S49 A" 0.003 7.870 eV
S50 A' 0.024 7.965 eV
S51 A" 0.001 8.002 eV
S52 A" 0.000 8.015 eV
S53 A' 0.087 8.069 eV
S54 A" 0.001 8.089 eV
S55 A" 0.000 8.123 eV
S56 A' 0.186 8.125 eV
S57 A" 0.002 8.149 eV
S58 A" 0.000 8.162 eV
S59 A' 0.242 8.196 eV
S60 A" 0.000 8.199 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -22996.64

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:26:54

Legacy ID None

System


Full Name Hexacyclo[12.8.0.02,11.03,8.04,22.015,20]docosa-1(14),2(11),3(8),4,6,9,12,15,17,19,21-undecaene

Short Name indeno(4,3,2,1-cdef)chrysene

Formula C22H12

Mass 276.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1694 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM