3,3-Dimethyl-11H-pyrano[3,2-a]carbazole-5-carbaldehyde (C18H15NO2) - excitons of #1699

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A" 0.000 3.954 eV
S2 A' 0.052 4.027 eV
S3 A' 0.093 4.265 eV
S4 A' 0.218 4.900 eV
S5 A' 0.538 5.051 eV
S6 A' 0.738 5.134 eV
S7 A' 0.166 5.525 eV
S8 A' 0.009 5.695 eV
S9 A" 0.001 5.811 eV
S10 A" 0.000 5.814 eV
S11 A' 0.460 6.005 eV
S12 A" 0.001 6.303 eV
S13 A' 0.112 6.316 eV
S14 A' 0.100 6.362 eV
S15 A' 0.671 6.499 eV
S16 A" 0.002 6.520 eV
S17 A' 0.009 6.781 eV
S18 A" 0.000 6.906 eV
S19 A' 0.016 6.952 eV
S20 A" 0.000 7.043 eV
S21 A" 0.001 7.128 eV
S22 A' 0.129 7.150 eV
S23 A" 0.003 7.181 eV
S24 A" 0.001 7.304 eV
S25 A" 0.000 7.344 eV
S26 A" 0.000 7.361 eV
S27 A' 0.188 7.378 eV
S28 A' 0.128 7.415 eV
S29 A" 0.000 7.421 eV
S30 A" 0.003 7.563 eV
S31 A' 0.028 7.625 eV
S32 A" 0.002 7.632 eV
S33 A' 0.004 7.641 eV
S34 A" 0.001 7.718 eV
S35 A" 0.000 7.736 eV
S36 A" 0.005 7.793 eV
S37 A' 0.347 7.808 eV
S38 A" 0.001 7.891 eV
S39 A' 0.071 7.912 eV
S40 A" 0.002 7.923 eV
S41 A' 0.076 7.973 eV
S42 A' 0.048 8.009 eV
S43 A" 0.003 8.051 eV
S44 A" 0.000 8.073 eV
S45 A' 0.202 8.085 eV
S46 A" 0.000 8.110 eV
S47 A" 0.001 8.173 eV
S48 A' 0.022 8.206 eV
S49 A' 0.029 8.255 eV
S50 A" 0.000 8.269 eV
S51 A" 0.002 8.284 eV
S52 A" 0.000 8.302 eV
S53 A" 0.001 8.312 eV
S54 A" 0.001 8.359 eV
S55 A" 0.010 8.371 eV
S56 A' 0.040 8.401 eV
S57 A" 0.001 8.431 eV
S58 A" 0.000 8.463 eV
S59 A' 0.023 8.464 eV
S60 A" 0.001 8.485 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -24482.45

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:28:02

Legacy ID None

System


Full Name 3,3-Dimethyl-11H-pyrano[3,2-a]carbazole-5-carbaldehyde

Short Name murrayacine

Formula C18H15NO2

Mass 277.3 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1699 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM