Naphtho[2,1-a]azulene (C18H12) - excitons of #1708

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.015 2.411 eV
S2 A' 0.006 3.462 eV
S3 A' 0.326 4.419 eV
S4 A' 0.336 4.524 eV
S5 A' 0.736 4.661 eV
S6 A' 1.427 4.852 eV
S7 A' 0.044 5.259 eV
S8 A' 0.019 5.431 eV
S9 A' 0.045 5.566 eV
S10 A' 0.121 5.885 eV
S11 A' 0.015 6.089 eV
S12 A" 0.001 6.180 eV
S13 A" 0.000 6.192 eV
S14 A' 0.112 6.282 eV
S15 A' 0.037 6.374 eV
S16 A" 0.000 6.396 eV
S17 A" 0.000 6.612 eV
S18 A' 0.049 6.613 eV
S19 A' 1.060 6.708 eV
S20 A" 0.002 6.788 eV
S21 A' 0.070 6.884 eV
S22 A" 0.000 6.903 eV
S23 A' 0.001 6.921 eV
S24 A" 0.000 7.009 eV
S25 A" 0.002 7.059 eV
S26 A" 0.000 7.107 eV
S27 A" 0.000 7.162 eV
S28 A' 0.124 7.174 eV
S29 A" 0.000 7.201 eV
S30 A" 0.001 7.289 eV
S31 A' 0.125 7.340 eV
S32 A' 0.306 7.435 eV
S33 A" 0.000 7.454 eV
S34 A" 0.000 7.525 eV
S35 A" 0.000 7.555 eV
S36 A" 0.000 7.595 eV
S37 A' 0.295 7.642 eV
S38 A" 0.000 7.647 eV
S39 A" 0.004 7.706 eV
S40 A" 0.001 7.731 eV
S41 A' 0.078 7.732 eV
S42 A" 0.004 7.810 eV
S43 A' 0.463 7.858 eV
S44 A" 0.000 7.881 eV
S45 A' 0.004 7.986 eV
S46 A" 0.005 8.021 eV
S47 A' 0.029 8.060 eV
S48 A" 0.000 8.111 eV
S49 A" 0.000 8.125 eV
S50 A" 0.000 8.162 eV
S51 A" 0.000 8.193 eV
S52 A" 0.004 8.288 eV
S53 A" 0.001 8.304 eV
S54 A" 0.002 8.327 eV
S55 A' 0.077 8.350 eV
S56 A" 0.001 8.421 eV
S57 A' 0.003 8.437 eV
S58 A" 0.004 8.447 eV
S59 A" 0.000 8.462 eV
S60 A" 0.002 8.535 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -18848.01

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:30:15

Legacy ID None

System


Full Name Naphtho[2,1-a]azulene

Short Name naphth(2,1-a)azulene

Formula C18H12

Mass 228.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1708 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM