Hexacyclo[11.10.1.02,7.09,24.014,23.016,21]tetracosa-1(24),2,4,6,8,10,12,14,16,18,20,22-dodecaene (C24H14) - excitons of #1709

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.393 3.275 eV
S2 A' 0.015 3.693 eV
S3 A' 0.022 4.057 eV
S4 A' 0.096 4.224 eV
S5 A' 0.014 4.318 eV
S6 A' 0.211 4.824 eV
S7 A' 0.482 5.099 eV
S8 A' 0.792 5.194 eV
S9 A' 0.363 5.338 eV
S10 A' 0.005 5.488 eV
S11 A' 0.734 5.553 eV
S12 A' 0.083 5.855 eV
S13 A' 0.316 5.910 eV
S14 A' 0.137 6.052 eV
S15 A' 0.556 6.105 eV
S16 A" 0.000 6.147 eV
S17 A' 0.291 6.183 eV
S18 A' 0.130 6.281 eV
S19 A" 0.000 6.330 eV
S20 A' 0.361 6.375 eV
S21 A' 0.107 6.441 eV
S22 A' 0.226 6.497 eV
S23 A' 0.084 6.588 eV
S24 A" 0.001 6.617 eV
S25 A' 0.415 6.650 eV
S26 A" 0.000 6.726 eV
S27 A' 0.081 6.742 eV
S28 A" 0.000 6.825 eV
S29 A' 0.337 6.832 eV
S30 A' 0.038 6.853 eV
S31 A" 0.000 6.881 eV
S32 A' 0.049 6.897 eV
S33 A" 0.000 6.960 eV
S34 A" 0.000 7.029 eV
S35 A" 0.000 7.121 eV
S36 A" 0.000 7.157 eV
S37 A' 0.030 7.160 eV
S38 A' 0.075 7.273 eV
S39 A' 0.188 7.311 eV
S40 A' 0.152 7.340 eV
S41 A" 0.000 7.372 eV
S42 A' 0.051 7.442 eV
S43 A" 0.000 7.449 eV
S44 A" 0.000 7.538 eV
S45 A' 0.078 7.585 eV
S46 A" 0.006 7.606 eV
S47 A' 0.081 7.620 eV
S48 A" 0.000 7.632 eV
S49 A" 0.002 7.665 eV
S50 A' 0.054 7.672 eV
S51 A" 0.000 7.683 eV
S52 A" 0.000 7.694 eV
S53 A' 0.004 7.730 eV
S54 A" 0.003 7.761 eV
S55 A" 0.003 7.854 eV
S56 A' 0.070 7.902 eV
S57 A" 0.000 7.928 eV
S58 A' 0.051 7.968 eV
S59 A" 0.001 7.991 eV
S60 A" 0.000 8.002 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25103.05

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:30:27

Legacy ID None

System


Full Name Hexacyclo[11.10.1.02,7.09,24.014,23.016,21]tetracosa-1(24),2,4,6,8,10,12,14,16,18,20,22-dodecaene

Short Name naphth(2,3-a)aceanthrylene

Formula C24H14

Mass 302.4 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1709 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM