10,11-Dithiapentacyclo[10.7.1.03,8.09,20.013,18]icosa-1(19),2,4,6,8,12(20),13,15,17-nonaene (C18H10S2) - excitons of #1711

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A1 0.203 2.631 eV
S2 B2 0.000 2.808 eV
S3 B1 0.067 3.530 eV
S4 B1 0.034 3.943 eV
S5 A2 0.000 4.320 eV
S6 B1 0.000 4.419 eV
S7 A1 0.005 4.458 eV
S8 B1 1.511 4.814 eV
S9 B2 0.000 4.931 eV
S10 A1 0.009 5.132 eV
S11 B1 0.643 5.178 eV
S12 A2 0.000 5.206 eV
S13 A1 0.000 5.279 eV
S14 B1 0.117 5.664 eV
S15 A2 0.000 5.773 eV
S16 A1 0.049 5.924 eV
S17 B1 1.056 6.058 eV
S18 A2 0.000 6.101 eV
S19 A1 0.000 6.127 eV
S20 A1 0.035 6.166 eV
S21 A2 0.000 6.291 eV
S22 A2 0.000 6.358 eV
S23 B2 0.002 6.363 eV
S24 B1 0.041 6.364 eV
S25 A2 0.000 6.464 eV
S26 B2 0.001 6.475 eV
S27 A2 0.000 6.546 eV
S28 B2 0.000 6.553 eV
S29 A1 0.117 6.615 eV
S30 B2 0.001 6.696 eV
S31 A2 0.000 6.716 eV
S32 B2 0.000 6.717 eV
S33 A1 0.406 6.805 eV
S34 A1 0.007 6.850 eV
S35 B1 0.063 6.870 eV
S36 B2 0.000 7.050 eV
S37 A2 0.000 7.146 eV
S38 A1 0.062 7.147 eV
S39 A2 0.000 7.175 eV
S40 B1 0.114 7.232 eV
S41 B2 0.001 7.255 eV
S42 A1 0.080 7.282 eV
S43 B2 0.000 7.293 eV
S44 B1 0.090 7.382 eV
S45 A2 0.000 7.432 eV
S46 B1 0.249 7.503 eV
S47 B2 0.013 7.522 eV
S48 A1 0.012 7.606 eV
S49 A2 0.000 7.611 eV
S50 B2 0.001 7.634 eV
S51 B2 0.001 7.663 eV
S52 B1 0.001 7.680 eV
S53 B1 0.073 7.710 eV
S54 A2 0.000 7.723 eV
S55 A1 0.002 7.768 eV
S56 A2 0.000 7.781 eV
S57 A1 0.047 7.791 eV
S58 B1 0.007 7.792 eV
S59 B2 0.009 7.805 eV
S60 B1 0.001 7.880 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -40489.00

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:31:01

Legacy ID None

System


Full Name 10,11-Dithiapentacyclo[10.7.1.03,8.09,20.013,18]icosa-1(19),2,4,6,8,12(20),13,15,17-nonaene

Short Name naphthaceno[5,6-cd]-1,2-dithiole

Formula C18H10S2

Mass 290.4 u

Point Group C2v

Orientation xz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1711 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM