Hexacyclo[14.7.1.02,15.04,13.06,11.020,24]tetracosa-1(23),2,4,6,8,10,12,14,16,18,20(24),21-dodecaene (C24H14) - excitons of #1721

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A1 0.288 3.588 eV
S2 B1 0.042 3.602 eV
S3 B1 0.007 4.266 eV
S4 A1 1.298 4.344 eV
S5 B1 0.000 4.517 eV
S6 B1 0.028 4.799 eV
S7 A1 0.819 5.027 eV
S8 B1 0.044 5.125 eV
S9 A1 0.786 5.263 eV
S10 A1 0.099 5.529 eV
S11 B1 0.099 5.636 eV
S12 B1 0.070 5.784 eV
S13 A1 1.045 5.800 eV
S14 B1 0.230 5.876 eV
S15 A1 0.094 6.092 eV
S16 B1 0.107 6.280 eV
S17 A1 0.242 6.400 eV
S18 A1 0.007 6.463 eV
S19 B2 0.000 6.506 eV
S20 B1 0.147 6.517 eV
S21 B2 0.000 6.537 eV
S22 B1 0.192 6.556 eV
S23 A1 0.002 6.559 eV
S24 A2 0.000 6.643 eV
S25 B2 0.000 6.706 eV
S26 A2 0.000 6.713 eV
S27 B1 0.058 6.736 eV
S28 B1 0.043 6.748 eV
S29 A1 0.059 6.803 eV
S30 A2 0.000 6.820 eV
S31 A2 0.000 6.898 eV
S32 B2 0.000 6.982 eV
S33 A1 0.026 7.066 eV
S34 B2 0.000 7.068 eV
S35 A2 0.000 7.090 eV
S36 B1 0.494 7.187 eV
S37 A1 0.109 7.283 eV
S38 A2 0.000 7.294 eV
S39 A1 0.014 7.422 eV
S40 B1 0.122 7.478 eV
S41 A1 0.012 7.492 eV
S42 A2 0.000 7.503 eV
S43 B2 0.006 7.506 eV
S44 B2 0.001 7.519 eV
S45 A2 0.000 7.555 eV
S46 B1 0.058 7.596 eV
S47 A1 0.033 7.632 eV
S48 B1 0.459 7.702 eV
S49 B1 0.015 7.745 eV
S50 A2 0.000 7.778 eV
S51 B2 0.000 7.779 eV
S52 A1 0.026 7.784 eV
S53 A2 0.000 7.795 eV
S54 A2 0.000 7.808 eV
S55 B2 0.001 7.896 eV
S56 A2 0.000 7.932 eV
S57 A1 0.062 7.935 eV
S58 B2 0.003 7.987 eV
S59 A2 0.000 7.998 eV
S60 B2 0.000 8.012 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25103.11

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:34:06

Legacy ID None

System


Full Name Hexacyclo[14.7.1.02,15.04,13.06,11.020,24]tetracosa-1(23),2,4,6,8,10,12,14,16,18,20(24),21-dodecaene

Short Name naphtho[2,3-k]fluoranthene

Formula C24H14

Mass 302.4 u

Point Group C2v

Orientation zx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1721 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM