Pentacene-1-carbaldehyde (C23H14O) - excitons of #1726

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.131 2.511 eV
S2 A' 0.002 3.511 eV
S3 A' 0.030 3.529 eV
S4 A" 0.000 3.707 eV
S5 A' 0.005 3.834 eV
S6 A' 0.045 4.348 eV
S7 A' 1.204 4.707 eV
S8 A' 0.337 4.824 eV
S9 A' 3.491 4.888 eV
S10 A' 0.039 5.148 eV
S11 A" 0.000 5.251 eV
S12 A' 0.105 5.397 eV
S13 A' 0.004 5.436 eV
S14 A' 0.147 5.635 eV
S15 A' 0.058 5.661 eV
S16 A' 0.005 5.909 eV
S17 A" 0.000 5.985 eV
S18 A' 0.055 6.044 eV
S19 A" 0.000 6.069 eV
S20 A' 0.007 6.141 eV
S21 A" 0.000 6.203 eV
S22 A' 0.001 6.232 eV
S23 A' 0.031 6.334 eV
S24 A' 0.110 6.371 eV
S25 A" 0.000 6.372 eV
S26 A" 0.000 6.424 eV
S27 A" 0.000 6.537 eV
S28 A" 0.000 6.556 eV
S29 A' 0.006 6.566 eV
S30 A" 0.000 6.716 eV
S31 A' 0.351 6.720 eV
S32 A' 0.074 6.753 eV
S33 A" 0.000 6.757 eV
S34 A' 0.018 6.858 eV
S35 A' 0.008 6.884 eV
S36 A" 0.000 6.894 eV
S37 A" 0.000 6.894 eV
S38 A' 0.001 7.055 eV
S39 A" 0.000 7.078 eV
S40 A" 0.000 7.085 eV
S41 A' 0.027 7.125 eV
S42 A' 0.038 7.149 eV
S43 A' 0.112 7.254 eV
S44 A" 0.000 7.336 eV
S45 A" 0.000 7.378 eV
S46 A' 0.013 7.400 eV
S47 A' 0.023 7.466 eV
S48 A" 0.000 7.513 eV
S49 A" 0.000 7.525 eV
S50 A' 0.019 7.576 eV
S51 A' 0.013 7.595 eV
S52 A" 0.000 7.600 eV
S53 A' 0.083 7.699 eV
S54 A" 0.000 7.714 eV
S55 A' 0.012 7.746 eV
S56 A" 0.001 7.855 eV
S57 A' 0.002 7.859 eV
S58 A" 0.001 7.889 eV
S59 A" 0.001 7.907 eV
S60 A' 0.026 7.929 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -26112.82

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:35:20

Legacy ID None

System


Full Name Pentacene-1-carbaldehyde

Short Name pentacal

Formula C23H14O

Mass 306.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1726 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM