6-Thiapentacyclo[11.8.0.03,11.05,9.015,20]henicosa-1(21),2,4,7,9,11,13,15,17,19-decaene (C20H12S) - excitons of #1749

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.118 2.800 eV
S2 A' 0.001 3.632 eV
S3 A' 0.009 3.952 eV
S4 A' 0.047 4.272 eV
S5 A' 1.784 4.889 eV
S6 A" 0.000 4.980 eV
S7 A' 0.751 4.982 eV
S8 A' 2.143 5.026 eV
S9 A' 0.076 5.203 eV
S10 A' 0.008 5.466 eV
S11 A' 0.224 5.707 eV
S12 A' 0.002 5.855 eV
S13 A' 0.003 5.867 eV
S14 A' 0.054 6.084 eV
S15 A" 0.000 6.100 eV
S16 A" 0.000 6.134 eV
S17 A' 0.026 6.171 eV
S18 A' 0.215 6.373 eV
S19 A" 0.000 6.438 eV
S20 A" 0.000 6.472 eV
S21 A' 0.088 6.491 eV
S22 A" 0.000 6.534 eV
S23 A" 0.000 6.543 eV
S24 A' 0.032 6.558 eV
S25 A" 0.000 6.622 eV
S26 A" 0.000 6.769 eV
S27 A' 0.006 6.785 eV
S28 A" 0.000 6.830 eV
S29 A" 0.000 6.882 eV
S30 A' 0.017 6.887 eV
S31 A' 0.011 6.946 eV
S32 A' 0.010 7.013 eV
S33 A" 0.000 7.052 eV
S34 A' 0.012 7.084 eV
S35 A" 0.002 7.128 eV
S36 A' 0.036 7.149 eV
S37 A" 0.000 7.229 eV
S38 A' 0.008 7.232 eV
S39 A' 0.069 7.293 eV
S40 A" 0.000 7.361 eV
S41 A" 0.000 7.388 eV
S42 A' 0.029 7.484 eV
S43 A" 0.000 7.486 eV
S44 A' 0.048 7.595 eV
S45 A" 0.000 7.633 eV
S46 A" 0.000 7.697 eV
S47 A' 0.069 7.716 eV
S48 A' 0.030 7.774 eV
S49 A" 0.001 7.789 eV
S50 A" 0.000 7.848 eV
S51 A" 0.003 7.878 eV
S52 A' 0.019 7.892 eV
S53 A" 0.000 7.914 eV
S54 A" 0.003 7.934 eV
S55 A" 0.000 7.963 eV
S56 A' 0.004 7.969 eV
S57 A" 0.000 8.050 eV
S58 A' 0.037 8.090 eV
S59 A" 0.001 8.110 eV
S60 A" 0.006 8.177 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31758.71

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:40:42

Legacy ID None

System


Full Name 6-Thiapentacyclo[11.8.0.03,11.05,9.015,20]henicosa-1(21),2,4,7,9,11,13,15,17,19-decaene

Short Name tetraceno(2,3-b)thiophene

Formula C20H12S

Mass 284.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1749 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM