7-Thiapentacyclo[11.8.0.03,11.05,9.015,20]henicosa-1,3,5,8,10,12,14,16,18,20-decaene (C20H12S) - excitons of #1750

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B2 0.126 2.156 eV
S2 B2 0.000 3.373 eV
S3 B2 0.000 3.505 eV
S4 A1 0.072 3.536 eV
S5 B2 0.010 4.512 eV
S6 B2 0.027 4.656 eV
S7 A1 2.239 4.790 eV
S8 A1 2.984 4.980 eV
S9 B2 0.002 5.088 eV
S10 B2 0.000 5.216 eV
S11 B1 0.001 5.313 eV
S12 B2 0.085 5.454 eV
S13 B2 0.001 5.565 eV
S14 B1 0.000 5.754 eV
S15 B1 0.000 5.780 eV
S16 A1 0.000 5.795 eV
S17 A2 0.000 5.915 eV
S18 A1 0.005 6.156 eV
S19 B1 0.000 6.172 eV
S20 A2 0.000 6.188 eV
S21 B2 0.000 6.188 eV
S22 A2 0.000 6.242 eV
S23 B1 0.000 6.298 eV
S24 A1 0.088 6.318 eV
S25 A2 0.000 6.371 eV
S26 B2 0.010 6.378 eV
S27 B2 0.017 6.594 eV
S28 B2 0.176 6.642 eV
S29 B1 0.006 6.655 eV
S30 A2 0.000 6.733 eV
S31 B1 0.000 6.807 eV
S32 A1 0.000 6.828 eV
S33 B2 0.016 6.891 eV
S34 B1 0.000 6.914 eV
S35 A1 0.000 6.920 eV
S36 A2 0.000 6.985 eV
S37 A2 0.000 7.015 eV
S38 B2 0.019 7.032 eV
S39 A1 0.001 7.109 eV
S40 A2 0.000 7.147 eV
S41 A2 0.000 7.186 eV
S42 A1 0.005 7.265 eV
S43 A2 0.000 7.286 eV
S44 A1 0.087 7.339 eV
S45 B1 0.001 7.367 eV
S46 B2 0.028 7.405 eV
S47 B1 0.000 7.504 eV
S48 A2 0.000 7.585 eV
S49 A1 0.002 7.598 eV
S50 B1 0.000 7.627 eV
S51 B2 0.002 7.689 eV
S52 B1 0.003 7.696 eV
S53 A1 0.007 7.735 eV
S54 A2 0.000 7.816 eV
S55 B2 0.009 7.832 eV
S56 B1 0.000 7.864 eV
S57 A2 0.000 7.869 eV
S58 B1 0.017 7.881 eV
S59 A2 0.000 7.915 eV
S60 A1 0.075 7.998 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31758.01

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:40:56

Legacy ID None

System


Full Name 7-Thiapentacyclo[11.8.0.03,11.05,9.015,20]henicosa-1,3,5,8,10,12,14,16,18,20-decaene

Short Name tetraceno[2,3-c]thiophene

Formula C20H12S

Mass 284.4 u

Point Group C2v

Orientation zy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1750 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM