16-Thiapentacyclo[12.7.0.02,7.08,13.015,19]henicosa-1(14),2,4,6,8,10,12,15(19),17,20-decaene (C20H12S) - excitons of #1757

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.006 4.221 eV
S2 A' 0.056 4.420 eV
S3 A' 0.009 4.715 eV
S4 A' 0.030 4.954 eV
S5 A' 1.213 5.103 eV
S6 A' 0.572 5.258 eV
S7 A' 0.056 5.447 eV
S8 A' 0.219 5.529 eV
S9 A' 0.221 5.666 eV
S10 A' 0.054 5.947 eV
S11 A' 0.133 5.997 eV
S12 A" 0.000 6.049 eV
S13 A' 0.036 6.216 eV
S14 A' 0.083 6.259 eV
S15 A' 0.040 6.354 eV
S16 A' 0.054 6.414 eV
S17 A' 0.063 6.514 eV
S18 A" 0.000 6.580 eV
S19 A' 0.051 6.631 eV
S20 A' 0.143 6.732 eV
S21 A' 0.070 6.881 eV
S22 A" 0.000 6.946 eV
S23 A' 0.213 6.993 eV
S24 A' 0.076 7.041 eV
S25 A" 0.001 7.117 eV
S26 A' 0.064 7.159 eV
S27 A' 0.035 7.230 eV
S28 A" 0.001 7.243 eV
S29 A" 0.000 7.283 eV
S30 A' 0.362 7.284 eV
S31 A" 0.002 7.345 eV
S32 A' 0.759 7.374 eV
S33 A" 0.000 7.380 eV
S34 A" 0.001 7.388 eV
S35 A" 0.000 7.405 eV
S36 A' 0.051 7.466 eV
S37 A" 0.004 7.479 eV
S38 A" 0.004 7.492 eV
S39 A' 0.019 7.507 eV
S40 A" 0.003 7.514 eV
S41 A' 0.079 7.537 eV
S42 A" 0.000 7.551 eV
S43 A' 0.345 7.648 eV
S44 A" 0.000 7.679 eV
S45 A" 0.000 7.684 eV
S46 A" 0.002 7.713 eV
S47 A' 0.153 7.790 eV
S48 A" 0.000 7.860 eV
S49 A' 0.143 7.871 eV
S50 A' 0.194 7.912 eV
S51 A" 0.001 7.918 eV
S52 A' 0.434 7.962 eV
S53 A" 0.000 7.965 eV
S54 A" 0.000 7.979 eV
S55 A" 0.003 8.001 eV
S56 A" 0.002 8.026 eV
S57 A" 0.002 8.076 eV
S58 A" 0.000 8.131 eV
S59 A' 0.015 8.176 eV
S60 A" 0.004 8.181 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31759.24

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:42:28

Legacy ID None

System


Full Name 16-Thiapentacyclo[12.7.0.02,7.08,13.015,19]henicosa-1(14),2,4,6,8,10,12,15(19),17,20-decaene

Short Name triphenyleno[1,2-b]thiophene

Formula C20H12S

Mass 284.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1757 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM