Phenanthro[9,10-f][1]benzothiole (C20H12S) - excitons of #1759

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.011 4.210 eV
S2 A' 0.039 4.348 eV
S3 A' 0.018 4.680 eV
S4 A' 0.021 4.723 eV
S5 A' 0.650 5.063 eV
S6 A' 0.940 5.120 eV
S7 A' 0.684 5.361 eV
S8 A" 0.000 5.451 eV
S9 A' 0.243 5.631 eV
S10 A' 0.254 5.704 eV
S11 A' 0.052 6.000 eV
S12 A' 0.149 6.040 eV
S13 A' 0.108 6.230 eV
S14 A' 0.082 6.302 eV
S15 A" 0.000 6.329 eV
S16 A' 0.061 6.347 eV
S17 A' 0.012 6.526 eV
S18 A' 0.115 6.589 eV
S19 A' 0.049 6.653 eV
S20 A' 0.108 6.677 eV
S21 A' 0.209 6.809 eV
S22 A' 0.035 6.955 eV
S23 A" 0.000 7.014 eV
S24 A' 0.066 7.043 eV
S25 A" 0.000 7.070 eV
S26 A' 0.175 7.127 eV
S27 A" 0.000 7.193 eV
S28 A" 0.000 7.216 eV
S29 A' 0.328 7.221 eV
S30 A' 0.194 7.268 eV
S31 A" 0.001 7.298 eV
S32 A' 0.361 7.318 eV
S33 A' 0.363 7.332 eV
S34 A" 0.000 7.354 eV
S35 A" 0.003 7.365 eV
S36 A" 0.000 7.384 eV
S37 A' 0.090 7.387 eV
S38 A" 0.000 7.402 eV
S39 A" 0.002 7.444 eV
S40 A" 0.001 7.463 eV
S41 A" 0.000 7.511 eV
S42 A' 0.108 7.560 eV
S43 A" 0.000 7.622 eV
S44 A" 0.013 7.640 eV
S45 A' 0.037 7.647 eV
S46 A" 0.000 7.725 eV
S47 A" 0.000 7.798 eV
S48 A" 0.000 7.894 eV
S49 A' 0.106 7.916 eV
S50 A" 0.000 7.942 eV
S51 A' 0.054 7.957 eV
S52 A" 0.000 7.961 eV
S53 A' 0.074 8.018 eV
S54 A" 0.000 8.028 eV
S55 A" 0.000 8.060 eV
S56 A' 0.036 8.087 eV
S57 A" 0.001 8.112 eV
S58 A" 0.000 8.120 eV
S59 A" 0.004 8.156 eV
S60 A' 0.070 8.195 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31759.34

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:42:55

Legacy ID None

System


Full Name Phenanthro[9,10-f][1]benzothiole

Short Name triphenyleno[2,3-b]thiophene

Formula C20H12S

Mass 284.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1759 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM