19-Thiapentacyclo[14.2.1.05,18.06,11.012,17]nonadeca-1,3,5(18),6,8,10,12(17),13,15-nonaene (C18H10S) - excitons of #1760

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A1 0.004 4.226 eV
S2 B2 0.074 4.440 eV
S3 A1 0.002 4.862 eV
S4 B2 0.076 5.013 eV
S5 A1 0.519 5.074 eV
S6 A2 0.000 5.254 eV
S7 B2 0.039 5.438 eV
S8 B2 0.655 5.558 eV
S9 A1 0.042 5.701 eV
S10 B2 0.047 5.857 eV
S11 A1 0.883 5.988 eV
S12 B2 0.296 6.135 eV
S13 A1 0.283 6.174 eV
S14 B1 0.000 6.365 eV
S15 B2 0.192 6.480 eV
S16 A1 0.049 6.557 eV
S17 A1 0.003 6.701 eV
S18 B2 0.008 6.753 eV
S19 A1 0.107 6.982 eV
S20 A2 0.000 7.124 eV
S21 B2 0.080 7.136 eV
S22 B1 0.000 7.142 eV
S23 B2 0.083 7.181 eV
S24 A2 0.000 7.217 eV
S25 B1 0.003 7.298 eV
S26 A1 0.238 7.346 eV
S27 B2 0.063 7.366 eV
S28 B1 0.001 7.377 eV
S29 B1 0.000 7.384 eV
S30 A2 0.000 7.396 eV
S31 A2 0.000 7.401 eV
S32 B1 0.008 7.403 eV
S33 B2 0.122 7.454 eV
S34 A1 0.304 7.459 eV
S35 A2 0.000 7.524 eV
S36 B1 0.002 7.660 eV
S37 A1 0.131 7.700 eV
S38 A2 0.000 7.722 eV
S39 B1 0.008 7.736 eV
S40 B2 0.014 7.758 eV
S41 A2 0.000 7.764 eV
S42 B1 0.001 7.783 eV
S43 B2 0.429 7.814 eV
S44 B1 0.000 7.861 eV
S45 A1 0.062 7.908 eV
S46 A2 0.000 7.938 eV
S47 B1 0.001 7.962 eV
S48 A1 0.212 7.970 eV
S49 B1 0.000 8.036 eV
S50 B2 0.604 8.042 eV
S51 A2 0.000 8.089 eV
S52 A2 0.000 8.138 eV
S53 B1 0.006 8.172 eV
S54 A2 0.000 8.187 eV
S55 B1 0.000 8.261 eV
S56 A1 0.062 8.316 eV
S57 A2 0.000 8.344 eV
S58 B1 0.000 8.368 eV
S59 A2 0.000 8.492 eV
S60 B2 0.253 8.511 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -29653.21

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:43:08

Legacy ID None

System


Full Name 19-Thiapentacyclo[14.2.1.05,18.06,11.012,17]nonadeca-1,3,5(18),6,8,10,12(17),13,15-nonaene

Short Name triphenyleno(4,5-bcd)thiophene

Formula C18H10S

Mass 258.3 u

Point Group C2v

Orientation zy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1760 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM