11-Methylbenzo[a]pyrene (C21H14) - excitons of #1764

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.329 3.703 eV
S2 A' 0.097 3.816 eV
S3 A' 0.002 4.655 eV
S4 A' 0.048 4.894 eV
S5 A' 0.691 5.013 eV
S6 A' 0.108 5.176 eV
S7 A' 0.114 5.302 eV
S8 A' 0.062 5.367 eV
S9 A' 1.596 5.518 eV
S10 A' 0.001 5.692 eV
S11 A' 0.046 5.858 eV
S12 A' 0.040 6.321 eV
S13 A' 0.120 6.348 eV
S14 A' 0.156 6.415 eV
S15 A" 0.000 6.466 eV
S16 A' 0.029 6.590 eV
S17 A" 0.000 6.603 eV
S18 A' 0.052 6.619 eV
S19 A" 0.000 6.662 eV
S20 A" 0.001 6.681 eV
S21 A' 0.160 6.725 eV
S22 A" 0.000 6.762 eV
S23 A' 0.831 6.838 eV
S24 A' 0.022 6.932 eV
S25 A" 0.000 7.050 eV
S26 A" 0.000 7.123 eV
S27 A' 0.366 7.129 eV
S28 A" 0.000 7.201 eV
S29 A' 0.009 7.264 eV
S30 A" 0.000 7.298 eV
S31 A' 0.597 7.367 eV
S32 A" 0.000 7.443 eV
S33 A' 0.072 7.500 eV
S34 A" 0.000 7.516 eV
S35 A" 0.000 7.575 eV
S36 A' 0.078 7.582 eV
S37 A" 0.001 7.624 eV
S38 A' 0.092 7.657 eV
S39 A" 0.000 7.669 eV
S40 A" 0.000 7.722 eV
S41 A' 0.054 7.745 eV
S42 A" 0.000 7.791 eV
S43 A" 0.007 7.799 eV
S44 A' 0.641 7.831 eV
S45 A" 0.000 7.869 eV
S46 A" 0.004 7.897 eV
S47 A' 0.007 7.940 eV
S48 A" 0.000 7.982 eV
S49 A' 0.066 8.031 eV
S50 A" 0.000 8.049 eV
S51 A' 0.423 8.075 eV
S52 A" 0.000 8.114 eV
S53 A' 0.021 8.155 eV
S54 A" 0.011 8.159 eV
S55 A" 0.001 8.225 eV
S56 A' 0.029 8.246 eV
S57 A" 0.003 8.268 eV
S58 A" 0.000 8.303 eV
S59 A" 0.002 8.321 eV
S60 A" 0.000 8.325 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21992.82

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-11 07:59:47

Legacy ID None

System


Full Name 11-Methylbenzo[a]pyrene

Short Name 11-methylbenzo[a]pyrene

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1764 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM