5-Fluoro-18-nitrohexacyclo[12.12.0.02,7.08,13.015,20.021,26]hexacosa-1(14),2(7),3,5,8,10,12,15(20),16,18,21,23,25-tridecaene (C26H14FNO2) - excitons of #1821

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.327 3.719 eV
S2 0.030 3.916 eV
S3 0.000 4.090 eV
S4 0.017 4.239 eV
S5 0.460 4.478 eV
S6 0.011 4.603 eV
S7 0.302 4.623 eV
S8 0.180 4.803 eV
S9 0.110 5.011 eV
S10 0.109 5.060 eV
S11 0.028 5.114 eV
S12 0.545 5.246 eV
S13 0.112 5.270 eV
S14 0.356 5.411 eV
S15 0.161 5.507 eV
S16 0.379 5.639 eV
S17 0.093 5.683 eV
S18 0.026 5.792 eV
S19 0.064 5.867 eV
S20 0.027 5.917 eV
S21 0.045 6.019 eV
S22 0.001 6.082 eV
S23 0.134 6.117 eV
S24 0.003 6.187 eV
S25 0.104 6.304 eV
S26 0.065 6.354 eV
S27 0.007 6.376 eV
S28 0.036 6.434 eV
S29 0.054 6.498 eV
S30 0.036 6.517 eV
S31 0.053 6.566 eV
S32 0.019 6.659 eV
S33 0.045 6.707 eV
S34 0.026 6.801 eV
S35 0.010 6.869 eV
S36 0.028 6.882 eV
S37 0.023 6.897 eV
S38 0.143 6.933 eV
S39 0.681 6.976 eV
S40 0.065 7.001 eV
S41 0.178 7.034 eV
S42 0.238 7.101 eV
S43 0.091 7.140 eV
S44 0.309 7.161 eV
S45 0.020 7.200 eV
S46 0.278 7.211 eV
S47 0.016 7.273 eV
S48 0.181 7.286 eV
S49 0.003 7.311 eV
S50 0.100 7.343 eV
S51 0.038 7.351 eV
S52 0.088 7.359 eV
S53 0.027 7.376 eV
S54 0.034 7.415 eV
S55 0.003 7.448 eV
S56 0.018 7.463 eV
S57 0.026 7.484 eV
S58 0.005 7.514 eV
S59 0.013 7.522 eV
S60 0.147 7.543 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -35476.42

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:13:09

Legacy ID None

System


Full Name 5-Fluoro-18-nitrohexacyclo[12.12.0.02,7.08,13.015,20.021,26]hexacosa-1(14),2(7),3,5,8,10,12,15(20),16,18,21,23,25-tridecaene

Short Name CID102487100

Formula C26H14FNO2

Mass 391.4 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1821 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM