14,15-Dimethylhexacyclo[16.8.0.02,11.05,10.012,17.019,24]hexacosa-1,3,5,7,9,11,13,15,17,19,21,23,25-tridecaene (C28H20) - excitons of #1822

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.003 3.859 eV
S2 A" 0.019 3.998 eV
S3 A" 0.019 4.366 eV
S4 A' 0.481 4.559 eV
S5 A' 0.050 4.757 eV
S6 A" 1.360 4.765 eV
S7 A" 0.438 5.109 eV
S8 A' 0.281 5.285 eV
S9 A" 0.691 5.307 eV
S10 A' 0.041 5.416 eV
S11 A" 0.012 5.485 eV
S12 A' 0.008 5.491 eV
S13 A' 0.039 5.662 eV
S14 A" 0.075 5.674 eV
S15 A' 0.068 5.680 eV
S16 A" 0.002 5.935 eV
S17 A' 0.020 6.015 eV
S18 A" 0.002 6.096 eV
S19 A" 0.000 6.138 eV
S20 A' 0.006 6.158 eV
S21 A" 0.022 6.284 eV
S22 A" 0.009 6.515 eV
S23 A' 0.049 6.586 eV
S24 A" 0.009 6.601 eV
S25 A' 0.027 6.701 eV
S26 A" 0.099 6.707 eV
S27 A" 0.657 6.747 eV
S28 A' 0.153 6.751 eV
S29 A" 0.013 6.779 eV
S30 A" 0.153 6.805 eV
S31 A' 0.012 6.811 eV
S32 A' 0.082 6.885 eV
S33 A' 0.034 6.913 eV
S34 A" 0.002 7.001 eV
S35 A' 0.110 7.015 eV
S36 A' 0.002 7.040 eV
S37 A" 0.001 7.052 eV
S38 A' 0.035 7.068 eV
S39 A" 0.005 7.088 eV
S40 A' 0.076 7.095 eV
S41 A" 0.031 7.149 eV
S42 A' 0.082 7.184 eV
S43 A' 0.006 7.213 eV
S44 A' 0.008 7.262 eV
S45 A' 0.572 7.310 eV
S46 A" 0.243 7.323 eV
S47 A" 0.046 7.329 eV
S48 A' 1.139 7.375 eV
S49 A" 0.042 7.378 eV
S50 A" 0.040 7.418 eV
S51 A' 0.013 7.428 eV
S52 A" 0.051 7.462 eV
S53 A' 0.026 7.512 eV
S54 A" 0.009 7.555 eV
S55 A' 0.035 7.563 eV
S56 A" 0.011 7.593 eV
S57 A" 0.001 7.602 eV
S58 A' 0.008 7.630 eV
S59 A' 0.059 7.641 eV
S60 A' 0.043 7.669 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -29348.78

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:13:36

Legacy ID None

System


Full Name 14,15-Dimethylhexacyclo[16.8.0.02,11.05,10.012,17.019,24]hexacosa-1,3,5,7,9,11,13,15,17,19,21,23,25-tridecaene

Short Name CID10594445

Formula C28H20

Mass 356.5 u

Point Group Cs

Orientation zx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1822 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM