7-Methyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone (C25H12N2O4) - excitons of #1823

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 1.042 2.978 eV
S2 A" 0.000 3.890 eV
S3 A" 0.010 4.123 eV
S4 A" 0.055 4.149 eV
S5 A' 0.000 4.159 eV
S6 A' 0.000 4.177 eV
S7 A" 0.001 4.392 eV
S8 A' 0.000 4.470 eV
S9 A" 0.003 4.543 eV
S10 A' 0.000 4.612 eV
S11 A" 0.000 4.631 eV
S12 A" 0.005 4.730 eV
S13 A" 0.011 4.985 eV
S14 A" 0.001 5.321 eV
S15 A' 0.000 5.640 eV
S16 A" 0.489 5.646 eV
S17 A' 0.000 5.796 eV
S18 A" 0.000 5.825 eV
S19 A" 0.000 5.900 eV
S20 A' 0.001 5.922 eV
S21 A" 0.018 5.976 eV
S22 A' 0.108 6.052 eV
S23 A' 0.035 6.106 eV
S24 A' 0.170 6.140 eV
S25 A" 0.001 6.149 eV
S26 A' 0.000 6.157 eV
S27 A" 0.000 6.169 eV
S28 A" 0.263 6.236 eV
S29 A" 0.000 6.316 eV
S30 A' 0.436 6.391 eV
S31 A" 0.000 6.506 eV
S32 A' 1.200 6.513 eV
S33 A' 0.121 6.522 eV
S34 A' 0.027 6.601 eV
S35 A" 0.034 6.657 eV
S36 A" 0.037 6.699 eV
S37 A' 0.279 6.716 eV
S38 A' 0.374 6.721 eV
S39 A" 0.009 6.730 eV
S40 A" 0.369 6.773 eV
S41 A' 0.530 6.818 eV
S42 A" 0.140 6.826 eV
S43 A' 0.005 6.847 eV
S44 A' 0.043 6.901 eV
S45 A' 0.020 6.915 eV
S46 A" 0.001 6.964 eV
S47 A' 0.041 6.978 eV
S48 A" 0.007 7.053 eV
S49 A' 0.028 7.060 eV
S50 A' 0.007 7.098 eV
S51 A" 0.358 7.132 eV
S52 A" 0.023 7.145 eV
S53 A' 0.002 7.153 eV
S54 A' 0.001 7.195 eV
S55 A" 0.003 7.211 eV
S56 A' 0.014 7.245 eV
S57 A" 0.189 7.315 eV
S58 A' 0.000 7.325 eV
S59 A' 0.081 7.333 eV
S60 A" 0.007 7.334 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -37279.65

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:14:02

Legacy ID None

System


Full Name 7-Methyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone

Short Name CID105969

Formula C25H12N2O4

Mass 404.4 u

Point Group Cs

Orientation yz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1823 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM