3,15-Dithiaheptacyclo[14.12.0.02,14.04,13.06,11.018,27.020,25]octacosa-1(28),2(14),4,6,8,10,12,16,18,20,22,24,26-tridecaene (C26H14S2) - excitons of #1827

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.233 3.219 eV
S2 A' 0.019 3.788 eV
S3 A' 0.118 3.858 eV
S4 A' 0.387 4.086 eV
S5 A' 0.030 4.457 eV
S6 A" 0.000 4.629 eV
S7 A' 1.179 4.662 eV
S8 A' 1.874 4.710 eV
S9 A' 0.413 5.031 eV
S10 A' 0.567 5.133 eV
S11 A" 0.000 5.171 eV
S12 A' 0.015 5.283 eV
S13 A' 0.015 5.424 eV
S14 A' 0.008 5.527 eV
S15 A' 0.007 5.583 eV
S16 A' 0.015 5.672 eV
S17 A' 0.528 5.780 eV
S18 A' 0.043 5.839 eV
S19 A" 0.000 5.857 eV
S20 A' 0.207 5.948 eV
S21 A' 0.438 5.966 eV
S22 A" 0.000 6.043 eV
S23 A' 0.252 6.103 eV
S24 A' 0.072 6.244 eV
S25 A' 0.144 6.294 eV
S26 A' 0.165 6.324 eV
S27 A' 0.104 6.369 eV
S28 A" 0.000 6.376 eV
S29 A" 0.000 6.445 eV
S30 A" 0.000 6.482 eV
S31 A' 0.033 6.497 eV
S32 A' 0.038 6.586 eV
S33 A' 0.334 6.642 eV
S34 A" 0.000 6.646 eV
S35 A' 0.018 6.687 eV
S36 A" 0.000 6.731 eV
S37 A' 0.016 6.759 eV
S38 A' 0.014 6.785 eV
S39 A" 0.006 6.810 eV
S40 A" 0.002 6.822 eV
S41 A" 0.000 6.828 eV
S42 A" 0.000 6.875 eV
S43 A' 0.016 6.889 eV
S44 A' 0.133 6.921 eV
S45 A" 0.001 6.957 eV
S46 A" 0.000 6.972 eV
S47 A' 0.004 7.025 eV
S48 A' 0.005 7.036 eV
S49 A" 0.000 7.044 eV
S50 A" 0.001 7.064 eV
S51 A' 0.067 7.108 eV
S52 A' 0.098 7.137 eV
S53 A" 0.001 7.168 eV
S54 A' 0.008 7.183 eV
S55 A" 0.000 7.226 eV
S56 A' 0.027 7.263 eV
S57 A" 0.000 7.319 eV
S58 A" 0.000 7.324 eV
S59 A' 0.094 7.357 eV
S60 A" 0.000 7.370 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -48849.34

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:16:01

Legacy ID None

System


Full Name 3,15-Dithiaheptacyclo[14.12.0.02,14.04,13.06,11.018,27.020,25]octacosa-1(28),2(14),4,6,8,10,12,16,18,20,22,24,26-tridecaene

Short Name CID118333944

Formula C26H14S2

Mass 390.5 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1827 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM