21-Oxadecacyclo[25.6.2.02,11.04,9.012,32.015,31.018,30.019,23.024,29.028,33]pentatriaconta-1(33),2,4,6,8,10,12(32),13,15(31),16,18(30),19(23),24(29),25,27,34-hexadecaene-20,22-dione (C34H14O3) - excitons of #1843

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A1 0.148 3.207 eV
S2 B2 0.044 3.400 eV
S3 B2 0.191 3.880 eV
S4 A1 0.528 3.956 eV
S5 B2 0.064 4.168 eV
S6 A1 0.563 4.215 eV
S7 B1 0.000 4.398 eV
S8 B2 0.133 4.422 eV
S9 B2 0.029 4.685 eV
S10 A1 0.002 4.711 eV
S11 A1 1.079 4.769 eV
S12 B2 0.001 4.875 eV
S13 A1 0.848 4.904 eV
S14 B2 0.008 4.919 eV
S15 A2 0.000 4.978 eV
S16 B2 0.036 5.121 eV
S17 A1 0.044 5.206 eV
S18 A1 0.011 5.236 eV
S19 A1 0.611 5.343 eV
S20 B2 0.492 5.350 eV
S21 B2 0.004 5.447 eV
S22 A1 0.076 5.595 eV
S23 B2 0.004 5.601 eV
S24 A1 0.105 5.769 eV
S25 B2 0.000 5.779 eV
S26 B2 0.043 5.882 eV
S27 A1 0.810 5.949 eV
S28 B2 0.019 5.979 eV
S29 A1 0.514 6.047 eV
S30 B2 0.021 6.071 eV
S31 A2 0.000 6.093 eV
S32 A1 0.334 6.112 eV
S33 B2 0.069 6.200 eV
S34 B2 0.113 6.274 eV
S35 A1 0.000 6.275 eV
S36 B1 0.000 6.336 eV
S37 A1 0.054 6.347 eV
S38 B2 0.002 6.352 eV
S39 A1 0.002 6.398 eV
S40 A2 0.000 6.491 eV
S41 B2 0.007 6.525 eV
S42 A1 0.000 6.566 eV
S43 B2 0.065 6.567 eV
S44 B1 0.000 6.581 eV
S45 B1 0.000 6.658 eV
S46 A1 0.180 6.671 eV
S47 B2 0.000 6.691 eV
S48 A2 0.000 6.704 eV
S49 B2 0.031 6.782 eV
S50 A1 0.135 6.790 eV
S51 B1 0.000 6.790 eV
S52 A1 0.018 6.830 eV
S53 A2 0.000 6.863 eV
S54 B2 0.579 6.909 eV
S55 B1 0.000 6.959 eV
S56 B2 0.005 6.966 eV
S57 A1 0.016 6.974 eV
S58 B2 0.312 6.998 eV
S59 B2 0.378 7.089 eV
S60 A1 0.028 7.093 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -41616.16

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:23:47

Legacy ID None

System


Full Name 21-Oxadecacyclo[25.6.2.02,11.04,9.012,32.015,31.018,30.019,23.024,29.028,33]pentatriaconta-1(33),2,4,6,8,10,12(32),13,15(31),16,18(30),19(23),24(29),25,27,34-hexadecaene-20,22-dione

Short Name CID129630063

Formula C34H14O3

Mass 470.5 u

Point Group C2v

Orientation zy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1843 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM