15-Fluoro-9-oxaheptacyclo[16.8.0.02,11.03,8.04,25.012,17.021,26]hexacosa-1,3,5,7,11,13,15,17,19,21(26),22,24-dodecaen-10-one (C25H11FO2) - excitons of #1877

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.345 3.662 eV
S2 A' 0.068 3.778 eV
S3 A' 0.098 4.312 eV
S4 A' 0.055 4.702 eV
S5 A' 0.043 4.745 eV
S6 A' 0.033 4.834 eV
S7 A" 0.000 4.838 eV
S8 A' 0.844 4.902 eV
S9 A' 0.193 5.095 eV
S10 A' 0.015 5.194 eV
S11 A' 0.752 5.274 eV
S12 A' 0.128 5.355 eV
S13 A' 0.048 5.510 eV
S14 A' 0.011 5.727 eV
S15 A' 0.007 5.870 eV
S16 A' 0.159 5.967 eV
S17 A' 0.143 5.999 eV
S18 A' 0.141 6.070 eV
S19 A' 0.095 6.103 eV
S20 A' 0.141 6.209 eV
S21 A" 0.000 6.301 eV
S22 A' 0.032 6.367 eV
S23 A' 0.700 6.435 eV
S24 A" 0.000 6.517 eV
S25 A' 0.021 6.559 eV
S26 A" 0.000 6.580 eV
S27 A' 0.033 6.687 eV
S28 A" 0.000 6.717 eV
S29 A' 0.156 6.750 eV
S30 A' 0.263 6.767 eV
S31 A' 0.020 6.842 eV
S32 A' 0.629 6.894 eV
S33 A' 0.237 7.026 eV
S34 A" 0.000 7.059 eV
S35 A" 0.000 7.069 eV
S36 A' 0.254 7.081 eV
S37 A' 0.087 7.105 eV
S38 A" 0.001 7.209 eV
S39 A' 0.251 7.251 eV
S40 A" 0.001 7.272 eV
S41 A' 0.137 7.297 eV
S42 A' 0.195 7.359 eV
S43 A' 0.246 7.422 eV
S44 A" 0.001 7.424 eV
S45 A' 0.098 7.468 eV
S46 A" 0.000 7.475 eV
S47 A" 0.000 7.535 eV
S48 A" 0.001 7.564 eV
S49 A' 0.172 7.592 eV
S50 A" 0.000 7.597 eV
S51 A' 0.091 7.609 eV
S52 A" 0.000 7.668 eV
S53 A" 0.000 7.678 eV
S54 A' 0.630 7.697 eV
S55 A" 0.008 7.718 eV
S56 A' 0.138 7.750 eV
S57 A" 0.000 7.772 eV
S58 A' 0.039 7.818 eV
S59 A" 0.001 7.824 eV
S60 A" 0.000 7.843 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -32904.36

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:41:55

Legacy ID None

System


Full Name 15-Fluoro-9-oxaheptacyclo[16.8.0.02,11.03,8.04,25.012,17.021,26]hexacosa-1,3,5,7,11,13,15,17,19,21(26),22,24-dodecaen-10-one

Short Name CID154718007

Formula C25H11FO2

Mass 362.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1877 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM