7-[2-(Trifluoromethyl)phenyl]pentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C27H15F3) - excitons of #1878

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.014 3.975 eV
S2 0.199 4.162 eV
S3 0.133 4.174 eV
S4 0.138 4.775 eV
S5 0.249 5.078 eV
S6 0.050 5.118 eV
S7 0.365 5.201 eV
S8 0.487 5.462 eV
S9 0.023 5.502 eV
S10 0.103 5.527 eV
S11 0.076 5.669 eV
S12 0.113 5.697 eV
S13 0.334 5.753 eV
S14 0.075 5.900 eV
S15 0.138 5.957 eV
S16 0.408 5.982 eV
S17 0.174 6.162 eV
S18 0.263 6.193 eV
S19 0.011 6.256 eV
S20 0.019 6.263 eV
S21 0.016 6.292 eV
S22 0.044 6.358 eV
S23 0.155 6.442 eV
S24 0.002 6.513 eV
S25 0.132 6.571 eV
S26 0.141 6.597 eV
S27 0.107 6.683 eV
S28 0.020 6.721 eV
S29 0.016 6.740 eV
S30 0.056 6.838 eV
S31 0.019 6.865 eV
S32 0.356 6.871 eV
S33 0.004 6.964 eV
S34 0.340 7.114 eV
S35 0.014 7.134 eV
S36 0.003 7.192 eV
S37 0.005 7.212 eV
S38 0.451 7.228 eV
S39 0.046 7.263 eV
S40 0.001 7.312 eV
S41 0.048 7.355 eV
S42 0.013 7.366 eV
S43 0.016 7.372 eV
S44 0.167 7.410 eV
S45 0.025 7.467 eV
S46 0.072 7.479 eV
S47 0.004 7.494 eV
S48 0.075 7.499 eV
S49 0.073 7.512 eV
S50 0.356 7.560 eV
S51 0.289 7.571 eV
S52 0.088 7.592 eV
S53 0.062 7.637 eV
S54 0.075 7.648 eV
S55 0.770 7.652 eV
S56 0.004 7.698 eV
S57 0.005 7.715 eV
S58 0.018 7.740 eV
S59 0.015 7.755 eV
S60 0.063 7.788 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -36382.94

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:42:20

Legacy ID None

System


Full Name 7-[2-(Trifluoromethyl)phenyl]pentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name CID154719995

Formula C27H15F3

Mass 396.4 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1878 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM