6,8-Difluoro-13-(6-methylcyclohexa-2,4-dien-1-yl)heptacyclo[12.10.1.13,7.02,12.015,20.021,25.011,26]hexacosa-1(24),2(12),3(26),4,6,8,10,13,15,17,19,21(25),22-tridecaene (C33H20F2) - excitons of #1889

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.131 3.241 eV
S2 0.237 3.621 eV
S3 0.153 3.813 eV
S4 0.332 4.178 eV
S5 0.013 4.261 eV
S6 0.019 4.490 eV
S7 0.216 4.592 eV
S8 0.106 4.839 eV
S9 0.079 4.970 eV
S10 0.045 5.055 eV
S11 0.124 5.116 eV
S12 0.030 5.135 eV
S13 0.046 5.165 eV
S14 0.128 5.277 eV
S15 0.311 5.448 eV
S16 0.140 5.503 eV
S17 0.335 5.556 eV
S18 0.081 5.671 eV
S19 0.064 5.786 eV
S20 0.121 5.839 eV
S21 0.092 5.859 eV
S22 0.461 6.027 eV
S23 0.063 6.071 eV
S24 0.012 6.150 eV
S25 0.052 6.179 eV
S26 0.038 6.194 eV
S27 0.139 6.221 eV
S28 0.016 6.248 eV
S29 0.325 6.393 eV
S30 0.175 6.436 eV
S31 0.242 6.475 eV
S32 0.181 6.531 eV
S33 0.025 6.579 eV
S34 0.190 6.580 eV
S35 0.087 6.629 eV
S36 0.066 6.683 eV
S37 0.004 6.695 eV
S38 0.008 6.718 eV
S39 0.141 6.773 eV
S40 0.007 6.794 eV
S41 0.439 6.830 eV
S42 0.004 6.855 eV
S43 0.108 6.885 eV
S44 0.000 6.951 eV
S45 0.021 6.990 eV
S46 0.154 6.999 eV
S47 0.041 7.026 eV
S48 0.065 7.035 eV
S49 0.031 7.067 eV
S50 0.243 7.084 eV
S51 0.095 7.088 eV
S52 0.060 7.117 eV
S53 0.006 7.168 eV
S54 0.056 7.181 eV
S55 0.056 7.230 eV
S56 0.013 7.247 eV
S57 0.007 7.252 eV
S58 0.026 7.278 eV
S59 0.007 7.286 eV
S60 0.004 7.319 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -39966.14

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:47:23

Legacy ID None

System


Full Name 6,8-Difluoro-13-(6-methylcyclohexa-2,4-dien-1-yl)heptacyclo[12.10.1.13,7.02,12.015,20.021,25.011,26]hexacosa-1(24),2(12),3(26),4,6,8,10,13,15,17,19,21(25),22-tridecaene

Short Name CID164089052

Formula C33H20F2

Mass 454.5 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1889 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM