5,20-Dimethyl-15,30-diazaoctacyclo[14.14.2.02,7.08,32.09,14.017,22.023,31.024,29]dotriaconta-1(30),2(7),3,5,8(32),9,11,13,15,17(22),18,20,23(31),24,26,28-hexadecaene (C32H20N2) - excitons of #1896

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B 0.210 3.533 eV
S2 B 0.240 3.659 eV
S3 A 0.010 4.048 eV
S4 A 0.001 4.118 eV
S5 A 0.024 4.360 eV
S6 B 0.001 4.450 eV
S7 A 0.011 4.481 eV
S8 A 0.003 4.575 eV
S9 B 0.571 4.712 eV
S10 B 1.236 4.837 eV
S11 A 0.001 4.919 eV
S12 B 1.012 4.994 eV
S13 B 0.009 5.112 eV
S14 A 0.050 5.117 eV
S15 A 0.002 5.257 eV
S16 A 0.034 5.344 eV
S17 B 0.267 5.361 eV
S18 B 0.494 5.440 eV
S19 A 0.010 5.465 eV
S20 B 0.015 5.524 eV
S21 B 0.093 5.642 eV
S22 A 0.022 5.661 eV
S23 A 0.023 5.778 eV
S24 B 0.037 5.794 eV
S25 A 0.004 5.920 eV
S26 B 0.568 5.920 eV
S27 B 0.047 6.015 eV
S28 A 0.008 6.070 eV
S29 A 0.006 6.113 eV
S30 B 0.183 6.134 eV
S31 A 0.002 6.189 eV
S32 A 0.000 6.206 eV
S33 B 0.656 6.210 eV
S34 B 0.105 6.329 eV
S35 B 0.023 6.414 eV
S36 A 0.001 6.432 eV
S37 A 0.018 6.446 eV
S38 A 0.000 6.473 eV
S39 B 0.233 6.567 eV
S40 A 0.004 6.586 eV
S41 B 0.078 6.600 eV
S42 B 0.090 6.650 eV
S43 B 0.117 6.712 eV
S44 A 0.040 6.752 eV
S45 B 0.023 6.759 eV
S46 A 0.006 6.774 eV
S47 B 0.237 6.813 eV
S48 A 0.005 6.856 eV
S49 B 0.221 6.874 eV
S50 A 0.007 6.944 eV
S51 A 0.014 6.958 eV
S52 B 0.304 6.971 eV
S53 A 0.002 6.975 eV
S54 B 0.076 7.027 eV
S55 A 0.000 7.070 eV
S56 A 0.007 7.136 eV
S57 B 0.035 7.154 eV
S58 B 0.018 7.161 eV
S59 A 0.003 7.177 eV
S60 A 0.000 7.198 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -36476.69

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:51:44

Legacy ID None

System


Full Name 5,20-Dimethyl-15,30-diazaoctacyclo[14.14.2.02,7.08,32.09,14.017,22.023,31.024,29]dotriaconta-1(30),2(7),3,5,8(32),9,11,13,15,17(22),18,20,23(31),24,26,28-hexadecaene

Short Name CID192549

Formula C32H20N2

Mass 432.5 u

Point Group C2

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1896 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM