Octacyclo[15.13.1.118,26.02,7.09,31.010,15.019,24.030,32]dotriaconta-1(31),2,4,6,8,10,12,14,16,18(32),19,21,23,25,27,29-hexadecaene (C32H18) - excitons of #1898

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.613 2.773 eV
S2 0.010 3.473 eV
S3 0.000 3.644 eV
S4 0.007 3.756 eV
S5 0.000 3.893 eV
S6 0.073 4.158 eV
S7 0.251 4.362 eV
S8 0.045 4.497 eV
S9 0.020 4.640 eV
S10 0.035 4.704 eV
S11 0.032 4.891 eV
S12 0.476 4.994 eV
S13 0.436 5.114 eV
S14 0.005 5.153 eV
S15 0.033 5.338 eV
S16 0.420 5.403 eV
S17 0.137 5.421 eV
S18 0.025 5.484 eV
S19 0.332 5.555 eV
S20 0.299 5.616 eV
S21 0.146 5.691 eV
S22 0.088 5.776 eV
S23 0.403 5.865 eV
S24 0.059 5.952 eV
S25 0.103 6.027 eV
S26 0.162 6.043 eV
S27 1.193 6.070 eV
S28 0.037 6.160 eV
S29 0.159 6.202 eV
S30 0.412 6.226 eV
S31 0.014 6.281 eV
S32 0.003 6.319 eV
S33 0.083 6.335 eV
S34 0.003 6.368 eV
S35 0.230 6.382 eV
S36 0.278 6.440 eV
S37 0.037 6.451 eV
S38 0.243 6.468 eV
S39 0.129 6.488 eV
S40 0.020 6.506 eV
S41 0.023 6.566 eV
S42 0.008 6.569 eV
S43 0.046 6.582 eV
S44 0.039 6.616 eV
S45 0.133 6.629 eV
S46 0.426 6.722 eV
S47 0.255 6.745 eV
S48 0.064 6.768 eV
S49 0.081 6.802 eV
S50 0.011 6.831 eV
S51 0.030 6.856 eV
S52 0.006 6.889 eV
S53 0.119 6.927 eV
S54 0.050 6.958 eV
S55 0.033 7.029 eV
S56 0.070 7.037 eV
S57 0.039 7.050 eV
S58 0.042 7.065 eV
S59 0.018 7.097 eV
S60 0.098 7.138 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -33463.15

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 07:52:57

Legacy ID None

System


Full Name Octacyclo[15.13.1.118,26.02,7.09,31.010,15.019,24.030,32]dotriaconta-1(31),2,4,6,8,10,12,14,16,18(32),19,21,23,25,27,29-hexadecaene

Short Name CID21082929

Formula C32H18

Mass 402.5 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1898 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM