21,22-Difluoro-5-phenylheptacyclo[14.10.2.02,15.04,13.06,11.020,28.023,27]octacosa-1(27),2,4,6,8,10,12,14,16(28),17,19,21,23,25-tetradecaene (C34H18F2) - excitons of #1967

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.080 3.310 eV
S2 A' 0.006 3.591 eV
S3 A' 0.681 4.142 eV
S4 A' 0.772 4.201 eV
S5 A' 0.149 4.334 eV
S6 A' 0.002 4.613 eV
S7 A' 0.122 4.721 eV
S8 A' 0.141 4.818 eV
S9 A' 0.063 4.868 eV
S10 A" 0.000 5.126 eV
S11 A' 0.174 5.139 eV
S12 A" 0.000 5.146 eV
S13 A' 0.012 5.230 eV
S14 A' 1.002 5.293 eV
S15 A' 0.179 5.370 eV
S16 A' 0.877 5.436 eV
S17 A' 0.226 5.487 eV
S18 A" 0.000 5.539 eV
S19 A' 0.272 5.552 eV
S20 A' 0.000 5.642 eV
S21 A' 0.008 5.764 eV
S22 A' 0.133 5.937 eV
S23 A' 0.056 5.970 eV
S24 A' 0.018 5.997 eV
S25 A' 0.296 6.095 eV
S26 A' 0.791 6.178 eV
S27 A' 0.014 6.195 eV
S28 A" 0.001 6.216 eV
S29 A' 0.034 6.329 eV
S30 A" 0.003 6.366 eV
S31 A" 0.003 6.376 eV
S32 A' 0.083 6.382 eV
S33 A' 0.091 6.471 eV
S34 A" 0.000 6.493 eV
S35 A' 0.064 6.512 eV
S36 A' 0.076 6.554 eV
S37 A' 0.019 6.595 eV
S38 A' 0.005 6.631 eV
S39 A" 0.003 6.644 eV
S40 A" 0.000 6.645 eV
S41 A' 0.024 6.658 eV
S42 A" 0.001 6.671 eV
S43 A' 0.019 6.688 eV
S44 A' 0.023 6.743 eV
S45 A" 0.001 6.755 eV
S46 A' 0.010 6.842 eV
S47 A" 0.000 6.885 eV
S48 A' 0.613 6.899 eV
S49 A' 0.391 6.948 eV
S50 A" 0.003 6.949 eV
S51 A' 0.030 6.995 eV
S52 A" 0.013 6.998 eV
S53 A" 0.001 7.006 eV
S54 A' 0.010 7.016 eV
S55 A" 0.003 7.039 eV
S56 A' 0.019 7.103 eV
S57 A' 0.170 7.148 eV
S58 A' 0.012 7.215 eV
S59 A" 0.000 7.225 eV
S60 A' 0.094 7.241 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -40972.11

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:24:52

Legacy ID None

System


Full Name 21,22-Difluoro-5-phenylheptacyclo[14.10.2.02,15.04,13.06,11.020,28.023,27]octacosa-1(27),2,4,6,8,10,12,14,16(28),17,19,21,23,25-tetradecaene

Short Name CID57688923

Formula C34H18F2

Mass 464.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1967 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM