7,7-Difluoro-4,10-dithiophen-2-yl-3,11-dithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene (C17H8F2S4) - excitons of #1969

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B2 1.122 3.182 eV
S2 A1 0.007 4.413 eV
S3 B2 0.266 4.521 eV
S4 A1 0.001 4.668 eV
S5 A2 0.000 4.855 eV
S6 B2 0.201 5.170 eV
S7 A1 0.013 5.310 eV
S8 B2 0.085 5.406 eV
S9 A1 0.196 5.557 eV
S10 B1 0.000 5.570 eV
S11 A2 0.000 5.643 eV
S12 B2 0.000 5.712 eV
S13 B1 0.000 5.722 eV
S14 A1 0.009 6.007 eV
S15 B2 0.005 6.093 eV
S16 A1 0.017 6.287 eV
S17 A2 0.000 6.292 eV
S18 A2 0.000 6.369 eV
S19 B2 0.003 6.404 eV
S20 B1 0.000 6.431 eV
S21 B1 0.000 6.454 eV
S22 A2 0.000 6.463 eV
S23 A1 0.023 6.484 eV
S24 B2 0.189 6.507 eV
S25 A2 0.000 6.528 eV
S26 B1 0.000 6.598 eV
S27 A1 0.040 6.694 eV
S28 B2 0.057 6.778 eV
S29 A2 0.000 6.848 eV
S30 A1 0.002 6.879 eV
S31 B1 0.000 6.919 eV
S32 B1 0.000 6.965 eV
S33 B1 0.008 7.029 eV
S34 A2 0.000 7.103 eV
S35 A2 0.000 7.150 eV
S36 B2 0.102 7.201 eV
S37 A1 0.021 7.222 eV
S38 A2 0.000 7.256 eV
S39 B2 0.021 7.263 eV
S40 A2 0.000 7.299 eV
S41 B2 0.026 7.334 eV
S42 A1 0.008 7.366 eV
S43 A1 0.035 7.374 eV
S44 B1 0.000 7.457 eV
S45 B1 0.001 7.485 eV
S46 B1 0.000 7.507 eV
S47 A2 0.000 7.564 eV
S48 A2 0.000 7.572 eV
S49 B1 0.006 7.573 eV
S50 A1 0.374 7.654 eV
S51 B2 0.077 7.657 eV
S52 B1 0.000 7.702 eV
S53 A1 0.076 7.703 eV
S54 A2 0.000 7.704 eV
S55 B2 0.000 7.789 eV
S56 A2 0.000 7.843 eV
S57 B1 0.001 7.914 eV
S58 A2 0.000 7.917 eV
S59 A2 0.000 7.949 eV
S60 B2 0.103 7.956 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -66524.94

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:26:13

Legacy ID None

System


Full Name 7,7-Difluoro-4,10-dithiophen-2-yl-3,11-dithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene

Short Name CID57879116

Formula C17H8F2S4

Mass 378.5 u

Point Group C2v

Orientation yz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1969 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM