7-Methyl-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2(11),3,5,7,9,14,16,18,20,22-undecaene (C23H14S2) - excitons of #1970

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.333 3.665 eV
S2 A' 0.212 4.122 eV
S3 A' 0.011 4.164 eV
S4 A' 0.000 4.291 eV
S5 A" 0.000 4.721 eV
S6 A' 2.031 4.873 eV
S7 A' 0.000 4.994 eV
S8 A' 0.833 5.090 eV
S9 A" 0.000 5.255 eV
S10 A' 0.001 5.510 eV
S11 A' 0.197 5.571 eV
S12 A' 0.067 5.632 eV
S13 A' 0.101 5.700 eV
S14 A' 0.441 5.793 eV
S15 A" 0.000 5.873 eV
S16 A' 0.026 5.931 eV
S17 A' 0.006 6.004 eV
S18 A" 0.000 6.094 eV
S19 A' 0.909 6.108 eV
S20 A' 0.002 6.246 eV
S21 A' 0.006 6.324 eV
S22 A' 0.310 6.436 eV
S23 A' 0.000 6.479 eV
S24 A" 0.000 6.487 eV
S25 A' 0.000 6.557 eV
S26 A' 0.335 6.693 eV
S27 A" 0.000 6.750 eV
S28 A' 0.003 6.766 eV
S29 A" 0.001 6.787 eV
S30 A' 0.439 6.818 eV
S31 A" 0.000 6.899 eV
S32 A" 0.007 6.929 eV
S33 A" 0.000 6.940 eV
S34 A" 0.001 6.948 eV
S35 A' 0.000 6.949 eV
S36 A' 0.015 6.969 eV
S37 A" 0.002 7.027 eV
S38 A" 0.001 7.047 eV
S39 A' 0.022 7.076 eV
S40 A" 0.001 7.098 eV
S41 A' 0.107 7.137 eV
S42 A' 0.009 7.188 eV
S43 A" 0.000 7.194 eV
S44 A' 0.013 7.207 eV
S45 A' 0.059 7.280 eV
S46 A" 0.000 7.288 eV
S47 A' 0.366 7.326 eV
S48 A" 0.000 7.355 eV
S49 A" 0.000 7.394 eV
S50 A" 0.000 7.414 eV
S51 A" 0.000 7.454 eV
S52 A" 0.000 7.481 eV
S53 A" 0.000 7.513 eV
S54 A' 0.010 7.536 eV
S55 A" 0.001 7.597 eV
S56 A' 0.008 7.600 eV
S57 A' 0.007 7.617 eV
S58 A' 0.001 7.662 eV
S59 A" 0.000 7.665 eV
S60 A" 0.003 7.690 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -45738.97

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:26:30

Legacy ID None

System


Full Name 7-Methyl-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2(11),3,5,7,9,14,16,18,20,22-undecaene

Short Name CID57894795

Formula C23H14S2

Mass 354.5 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1970 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM