5,13,27-Trithiaheptacyclo[14.11.0.03,14.04,12.06,11.017,26.019,24]heptacosa-1,3(14),4(12),6,8,10,15,17,19,21,23,25-dodecaene (C24H12S3) - excitons of #1973

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.056 3.770 eV
S2 A' 0.930 3.968 eV
S3 A' 0.102 4.365 eV
S4 A' 0.685 4.588 eV
S5 A' 0.067 4.711 eV
S6 A" 0.000 4.912 eV
S7 A' 0.427 5.006 eV
S8 A" 0.000 5.037 eV
S9 A' 0.310 5.071 eV
S10 A' 0.558 5.230 eV
S11 A' 0.219 5.361 eV
S12 A' 0.304 5.412 eV
S13 A" 0.000 5.510 eV
S14 A' 0.073 5.576 eV
S15 A" 0.000 5.649 eV
S16 A' 0.153 5.662 eV
S17 A' 0.182 5.734 eV
S18 A' 0.245 5.855 eV
S19 A' 0.030 5.982 eV
S20 A' 0.016 6.005 eV
S21 A' 0.251 6.095 eV
S22 A" 0.000 6.120 eV
S23 A' 0.035 6.181 eV
S24 A" 0.000 6.225 eV
S25 A' 0.082 6.257 eV
S26 A' 0.004 6.393 eV
S27 A' 0.622 6.423 eV
S28 A' 0.081 6.462 eV
S29 A' 0.029 6.566 eV
S30 A' 0.098 6.626 eV
S31 A' 0.018 6.701 eV
S32 A" 0.000 6.702 eV
S33 A" 0.000 6.745 eV
S34 A' 0.220 6.748 eV
S35 A' 0.145 6.770 eV
S36 A" 0.000 6.802 eV
S37 A' 0.103 6.875 eV
S38 A" 0.000 6.878 eV
S39 A' 0.086 6.889 eV
S40 A" 0.000 6.905 eV
S41 A" 0.000 7.018 eV
S42 A' 0.056 7.043 eV
S43 A" 0.004 7.064 eV
S44 A' 0.133 7.096 eV
S45 A' 0.145 7.132 eV
S46 A" 0.003 7.160 eV
S47 A" 0.001 7.176 eV
S48 A" 0.000 7.184 eV
S49 A' 0.010 7.211 eV
S50 A" 0.001 7.241 eV
S51 A' 0.027 7.268 eV
S52 A" 0.000 7.302 eV
S53 A" 0.001 7.307 eV
S54 A' 0.105 7.317 eV
S55 A' 0.010 7.353 eV
S56 A" 0.000 7.366 eV
S57 A" 0.000 7.386 eV
S58 A' 0.087 7.434 eV
S59 A" 0.003 7.448 eV
S60 A" 0.000 7.475 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -57579.44

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:27:35

Legacy ID None

System


Full Name 5,13,27-Trithiaheptacyclo[14.11.0.03,14.04,12.06,11.017,26.019,24]heptacosa-1,3(14),4(12),6,8,10,15,17,19,21,23,25-dodecaene

Short Name CID57913352

Formula C24H12S3

Mass 396.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1973 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM