5,20-Diazaheptacyclo[16.12.0.03,16.04,13.06,11.019,28.021,26]triaconta-1(18),3(16),4(13),6,8,10,14,19(28),21,23,25,29-dodecaene-2,12,17,27-tetrone (C28H14N2O4) - excitons of #1988

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 Bu 0.513 2.889 eV
S2 Ag 0.000 2.987 eV
S3 Bg 0.000 3.413 eV
S4 Au 0.000 3.636 eV
S5 Bg 0.000 3.691 eV
S6 Au 0.000 3.789 eV
S7 Ag 0.000 4.028 eV
S8 Bu 0.014 4.341 eV
S9 Ag 0.000 4.345 eV
S10 Bu 0.200 4.357 eV
S11 Ag 0.000 4.450 eV
S12 Bu 0.666 4.612 eV
S13 Ag 0.000 4.649 eV
S14 Bu 0.071 4.799 eV
S15 Ag 0.000 4.804 eV
S16 Bu 0.604 5.053 eV
S17 Bg 0.000 5.058 eV
S18 Au 0.000 5.065 eV
S19 Ag 0.000 5.161 eV
S20 Bu 0.012 5.200 eV
S21 Bu 0.417 5.553 eV
S22 Au 0.000 5.603 eV
S23 Bg 0.000 5.628 eV
S24 Ag 0.000 5.648 eV
S25 Au 0.000 5.792 eV
S26 Bu 1.233 5.812 eV
S27 Bu 0.282 5.876 eV
S28 Ag 0.000 5.910 eV
S29 Bu 0.171 5.944 eV
S30 Ag 0.000 5.968 eV
S31 Au 0.001 5.976 eV
S32 Bg 0.000 5.994 eV
S33 Ag 0.000 6.073 eV
S34 Bu 0.242 6.161 eV
S35 Ag 0.000 6.221 eV
S36 Bu 0.086 6.234 eV
S37 Bu 0.725 6.331 eV
S38 Ag 0.000 6.365 eV
S39 Ag 0.000 6.391 eV
S40 Bg 0.000 6.411 eV
S41 Bu 0.015 6.418 eV
S42 Ag 0.000 6.432 eV
S43 Bu 0.086 6.515 eV
S44 Bg 0.000 6.544 eV
S45 Ag 0.000 6.572 eV
S46 Au 0.000 6.572 eV
S47 Bg 0.000 6.672 eV
S48 Ag 0.000 6.702 eV
S49 Bu 0.041 6.758 eV
S50 Au 0.000 6.872 eV
S51 Bg 0.000 6.915 eV
S52 Bu 0.233 6.930 eV
S53 Ag 0.000 6.935 eV
S54 Au 0.000 6.945 eV
S55 Bg 0.000 6.961 eV
S56 Bg 0.000 7.000 eV
S57 Au 0.004 7.002 eV
S58 Ag 0.000 7.016 eV
S59 Bu 0.150 7.054 eV
S60 Ag 0.000 7.061 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -40421.66

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:34:23

Legacy ID None

System


Full Name 5,20-Diazaheptacyclo[16.12.0.03,16.04,13.06,11.019,28.021,26]triaconta-1(18),3(16),4(13),6,8,10,14,19(28),21,23,25,29-dodecaene-2,12,17,27-tetrone

Short Name CID78143

Formula C28H14N2O4

Mass 442.4 u

Point Group C2h

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1988 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM