Heptacyclo[16.12.0.03,16.04,13.07,12.020,29.023,28]triaconta-1(18),2,4(13),5,7,9,11,14,16,19,21,23,25,27,29-pentadecaene (C30H18) - excitons of #2003

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.091 3.292 eV
S2 A' 0.003 3.606 eV
S3 A' 0.593 4.198 eV
S4 A' 0.057 4.246 eV
S5 A' 0.811 4.507 eV
S6 A' 2.597 4.521 eV
S7 A' 0.014 4.838 eV
S8 A' 0.264 4.870 eV
S9 A' 0.000 5.023 eV
S10 A' 0.170 5.141 eV
S11 A' 0.063 5.272 eV
S12 A' 0.313 5.421 eV
S13 A' 0.017 5.505 eV
S14 A' 0.197 5.587 eV
S15 A' 0.016 5.681 eV
S16 A' 0.226 5.713 eV
S17 A' 0.239 5.766 eV
S18 A' 0.009 5.864 eV
S19 A' 0.195 5.948 eV
S20 A' 0.012 6.081 eV
S21 A' 0.025 6.148 eV
S22 A' 0.289 6.234 eV
S23 A' 0.103 6.282 eV
S24 A" 0.000 6.291 eV
S25 A' 0.146 6.317 eV
S26 A" 0.000 6.350 eV
S27 A' 0.068 6.406 eV
S28 A' 0.150 6.441 eV
S29 A' 0.049 6.546 eV
S30 A" 0.000 6.553 eV
S31 A' 0.018 6.597 eV
S32 A' 0.055 6.610 eV
S33 A" 0.000 6.666 eV
S34 A' 0.113 6.730 eV
S35 A" 0.000 6.739 eV
S36 A' 0.186 6.779 eV
S37 A" 0.001 6.798 eV
S38 A' 0.250 6.878 eV
S39 A' 0.039 6.919 eV
S40 A' 0.000 6.959 eV
S41 A" 0.000 7.024 eV
S42 A" 0.002 7.032 eV
S43 A" 0.000 7.051 eV
S44 A' 0.064 7.083 eV
S45 A' 0.019 7.102 eV
S46 A' 0.094 7.129 eV
S47 A" 0.001 7.185 eV
S48 A' 0.143 7.206 eV
S49 A' 0.105 7.230 eV
S50 A" 0.000 7.253 eV
S51 A' 0.034 7.284 eV
S52 A" 0.000 7.307 eV
S53 A" 0.001 7.312 eV
S54 A' 0.019 7.331 eV
S55 A" 0.000 7.345 eV
S56 A" 0.003 7.355 eV
S57 A' 0.064 7.381 eV
S58 A' 0.039 7.385 eV
S59 A" 0.000 7.418 eV
S60 A' 0.029 7.475 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31390.00

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:41:48

Legacy ID None

System


Full Name Heptacyclo[16.12.0.03,16.04,13.07,12.020,29.023,28]triaconta-1(18),2,4(13),5,7,9,11,14,16,19,21,23,25,27,29-pentadecaene

Short Name benzo[a]naphtho[1,2-l]tetracene

Formula C30H18

Mass 378.5 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2003 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM