Heptacyclo[14.10.2.03,12.05,10.013,27.020,28.021,26]octacosa-1,3,5,7,9,11,13(27),14,16(28),17,19,21,23,25-tetradecaene (C28H16) - excitons of #2008

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.241 3.340 eV
S2 A' 0.003 3.674 eV
S3 A' 0.046 4.215 eV
S4 A' 0.110 4.339 eV
S5 A' 0.257 4.498 eV
S6 A' 1.627 4.623 eV
S7 A' 0.312 4.763 eV
S8 A' 0.176 4.865 eV
S9 A' 0.029 5.069 eV
S10 A' 0.049 5.155 eV
S11 A' 0.978 5.272 eV
S12 A' 0.017 5.483 eV
S13 A' 0.164 5.550 eV
S14 A' 0.063 5.619 eV
S15 A' 0.451 5.663 eV
S16 A' 0.041 5.798 eV
S17 A' 0.007 5.863 eV
S18 A' 0.060 5.911 eV
S19 A' 0.154 6.014 eV
S20 A' 0.410 6.120 eV
S21 A' 0.094 6.247 eV
S22 A" 0.000 6.292 eV
S23 A' 0.046 6.300 eV
S24 A' 0.292 6.379 eV
S25 A" 0.000 6.439 eV
S26 A' 0.056 6.476 eV
S27 A' 0.285 6.526 eV
S28 A" 0.000 6.526 eV
S29 A' 0.144 6.571 eV
S30 A' 0.261 6.604 eV
S31 A" 0.000 6.631 eV
S32 A' 0.100 6.669 eV
S33 A" 0.000 6.740 eV
S34 A' 0.066 6.748 eV
S35 A" 0.000 6.823 eV
S36 A' 0.130 6.875 eV
S37 A' 0.248 6.948 eV
S38 A" 0.000 6.967 eV
S39 A' 0.096 7.001 eV
S40 A' 0.037 7.007 eV
S41 A" 0.000 7.052 eV
S42 A" 0.000 7.117 eV
S43 A' 0.043 7.161 eV
S44 A' 0.071 7.235 eV
S45 A" 0.002 7.242 eV
S46 A' 0.288 7.258 eV
S47 A" 0.000 7.272 eV
S48 A' 0.104 7.299 eV
S49 A' 0.061 7.329 eV
S50 A" 0.001 7.380 eV
S51 A' 0.075 7.392 eV
S52 A" 0.004 7.420 eV
S53 A' 0.106 7.428 eV
S54 A" 0.003 7.459 eV
S55 A' 0.036 7.466 eV
S56 A' 0.124 7.513 eV
S57 A" 0.001 7.523 eV
S58 A' 0.168 7.531 eV
S59 A" 0.001 7.561 eV
S60 A" 0.000 7.572 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -29283.98

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:44:17

Legacy ID None

System


Full Name Heptacyclo[14.10.2.03,12.05,10.013,27.020,28.021,26]octacosa-1,3,5,7,9,11,13(27),14,16(28),17,19,21,23,25-tetradecaene

Short Name benzo[e]naphtho[2,3-a]pyrene

Formula C28H16

Mass 352.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2008 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM