Heptacyclo[16.12.0.03,16.04,13.06,11.020,29.022,27]triaconta-1(30),2,4,6,8,10,12,14,16,18,20,22,24,26,28-pentadecaene (C30H18) - excitons of #2009

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.088 2.787 eV
S2 A' 0.004 3.326 eV
S3 A' 0.551 3.896 eV
S4 A' 1.794 4.001 eV
S5 A' 0.438 4.036 eV
S6 A' 0.104 4.170 eV
S7 A' 0.062 4.302 eV
S8 A' 0.031 4.824 eV
S9 A' 1.234 4.917 eV
S10 A' 0.239 4.995 eV
S11 A' 0.290 5.087 eV
S12 A' 1.199 5.135 eV
S13 A' 0.166 5.427 eV
S14 A' 0.063 5.483 eV
S15 A' 0.011 5.500 eV
S16 A' 0.161 5.600 eV
S17 A' 0.035 5.675 eV
S18 A' 0.203 5.838 eV
S19 A' 0.058 5.867 eV
S20 A' 0.070 5.909 eV
S21 A' 0.241 6.005 eV
S22 A" 0.000 6.069 eV
S23 A" 0.000 6.101 eV
S24 A' 0.063 6.150 eV
S25 A' 0.185 6.195 eV
S26 A' 0.209 6.263 eV
S27 A" 0.000 6.363 eV
S28 A' 0.078 6.366 eV
S29 A' 0.014 6.417 eV
S30 A" 0.000 6.430 eV
S31 A" 0.000 6.437 eV
S32 A' 0.102 6.438 eV
S33 A' 0.142 6.501 eV
S34 A" 0.000 6.541 eV
S35 A" 0.000 6.553 eV
S36 A' 0.018 6.598 eV
S37 A' 0.032 6.691 eV
S38 A' 0.000 6.728 eV
S39 A" 0.000 6.773 eV
S40 A" 0.000 6.803 eV
S41 A' 0.005 6.825 eV
S42 A' 0.012 6.875 eV
S43 A" 0.000 6.878 eV
S44 A' 0.059 6.893 eV
S45 A' 0.063 6.933 eV
S46 A' 0.034 6.961 eV
S47 A" 0.000 6.965 eV
S48 A" 0.000 6.995 eV
S49 A" 0.000 7.013 eV
S50 A' 0.021 7.028 eV
S51 A" 0.000 7.065 eV
S52 A' 0.051 7.068 eV
S53 A' 0.023 7.129 eV
S54 A" 0.000 7.149 eV
S55 A' 0.147 7.261 eV
S56 A' 0.112 7.289 eV
S57 A" 0.000 7.299 eV
S58 A' 0.033 7.304 eV
S59 A' 0.046 7.348 eV
S60 A' 0.040 7.413 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31389.57

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:44:41

Legacy ID None

System


Full Name Heptacyclo[16.12.0.03,16.04,13.06,11.020,29.022,27]triaconta-1(30),2,4,6,8,10,12,14,16,18,20,22,24,26,28-pentadecaene

Short Name benzo(p)hexaphene

Formula C30H18

Mass 378.5 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2009 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM