Heptacyclo[14.10.2.02,11.04,9.013,27.018,23.024,28]octacosa-1(27),2,4,6,8,10,12,14,16,18,20,22,24(28),25-tetradecaene (C28H16) - excitons of #2010

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.508 3.319 eV
S2 A' 0.114 3.467 eV
S3 A' 0.858 4.094 eV
S4 A' 0.001 4.355 eV
S5 A' 0.045 4.490 eV
S6 A' 0.869 4.580 eV
S7 A' 0.073 4.656 eV
S8 A' 1.019 4.796 eV
S9 A' 0.008 5.031 eV
S10 A' 0.011 5.111 eV
S11 A' 0.018 5.218 eV
S12 A' 0.159 5.318 eV
S13 A' 0.225 5.460 eV
S14 A' 0.667 5.648 eV
S15 A' 0.024 5.722 eV
S16 A' 1.001 5.751 eV
S17 A' 0.038 5.849 eV
S18 A' 0.011 5.943 eV
S19 A' 0.004 6.000 eV
S20 A' 0.045 6.175 eV
S21 A' 0.533 6.262 eV
S22 A" 0.000 6.274 eV
S23 A' 0.059 6.293 eV
S24 A" 0.000 6.426 eV
S25 A' 0.011 6.431 eV
S26 A' 0.132 6.468 eV
S27 A' 0.092 6.544 eV
S28 A' 0.076 6.559 eV
S29 A" 0.000 6.596 eV
S30 A' 0.019 6.608 eV
S31 A" 0.000 6.620 eV
S32 A" 0.000 6.679 eV
S33 A" 0.000 6.712 eV
S34 A' 0.149 6.744 eV
S35 A' 0.091 6.807 eV
S36 A' 0.056 6.828 eV
S37 A' 0.027 6.859 eV
S38 A" 0.001 6.894 eV
S39 A" 0.000 6.921 eV
S40 A" 0.001 6.946 eV
S41 A' 0.459 6.986 eV
S42 A" 0.000 7.045 eV
S43 A' 0.026 7.086 eV
S44 A' 0.197 7.130 eV
S45 A' 0.005 7.139 eV
S46 A' 0.046 7.171 eV
S47 A" 0.000 7.200 eV
S48 A" 0.000 7.276 eV
S49 A" 0.000 7.290 eV
S50 A' 0.042 7.327 eV
S51 A" 0.001 7.356 eV
S52 A" 0.000 7.364 eV
S53 A' 0.017 7.381 eV
S54 A' 0.032 7.407 eV
S55 A" 0.000 7.474 eV
S56 A' 0.101 7.486 eV
S57 A" 0.000 7.513 eV
S58 A' 0.026 7.552 eV
S59 A" 0.001 7.579 eV
S60 A" 0.000 7.589 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -29283.89

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:45:09

Legacy ID None

System


Full Name Heptacyclo[14.10.2.02,11.04,9.013,27.018,23.024,28]octacosa-1(27),2,4,6,8,10,12,14,16,18,20,22,24(28),25-tetradecaene

Short Name benzo[vwx]hexaphene

Formula C28H16

Mass 352.4 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2010 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM