Undecacyclo[22.10.2.02,7.08,33.010,31.013,30.016,29.019,28.021,26.025,34.027,32]hexatriaconta-1(34),2,4,6,8(33),9,11,13(30),14,16(29),17,19,21(26),22,24,27,31,35-octadecaene (C36H16) - excitons of #2013

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.003 3.266 eV
S2 A' 0.261 3.323 eV
S3 A' 0.053 4.035 eV
S4 A' 0.057 4.106 eV
S5 A' 0.016 4.261 eV
S6 A' 0.881 4.394 eV
S7 A' 0.744 4.451 eV
S8 A' 0.435 4.460 eV
S9 A' 0.369 4.576 eV
S10 A' 0.189 4.664 eV
S11 A' 0.133 4.700 eV
S12 A' 0.094 4.844 eV
S13 A' 0.048 4.982 eV
S14 A' 0.063 5.095 eV
S15 A' 0.013 5.148 eV
S16 A' 0.065 5.249 eV
S17 A' 0.010 5.283 eV
S18 A' 0.131 5.316 eV
S19 A' 0.005 5.411 eV
S20 A' 0.067 5.493 eV
S21 A' 0.025 5.622 eV
S22 A' 0.020 5.703 eV
S23 A' 0.068 5.741 eV
S24 A' 0.067 5.774 eV
S25 A' 0.304 5.788 eV
S26 A' 0.143 5.819 eV
S27 A' 0.076 5.851 eV
S28 A' 0.101 5.914 eV
S29 A' 0.038 5.972 eV
S30 A' 0.206 6.004 eV
S31 A' 0.002 6.076 eV
S32 A' 0.386 6.192 eV
S33 A' 0.162 6.214 eV
S34 A' 0.803 6.226 eV
S35 A' 0.004 6.280 eV
S36 A" 0.000 6.306 eV
S37 A' 0.067 6.334 eV
S38 A' 0.071 6.364 eV
S39 A' 0.369 6.400 eV
S40 A" 0.000 6.401 eV
S41 A' 0.046 6.501 eV
S42 A' 0.761 6.534 eV
S43 A' 0.478 6.612 eV
S44 A' 0.017 6.640 eV
S45 A" 0.000 6.658 eV
S46 A' 0.258 6.677 eV
S47 A" 0.000 6.689 eV
S48 A' 0.059 6.709 eV
S49 A' 0.498 6.724 eV
S50 A' 0.211 6.799 eV
S51 A" 0.000 6.825 eV
S52 A' 0.015 6.849 eV
S53 A" 0.000 6.876 eV
S54 A' 0.090 6.879 eV
S55 A' 0.220 6.897 eV
S56 A" 0.000 6.926 eV
S57 A' 0.380 6.971 eV
S58 A" 0.000 7.015 eV
S59 A' 0.133 7.040 eV
S60 A' 0.028 7.044 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -37580.89

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 08:46:45

Legacy ID None

System


Full Name Undecacyclo[22.10.2.02,7.08,33.010,31.013,30.016,29.019,28.021,26.025,34.027,32]hexatriaconta-1(34),2,4,6,8(33),9,11,13(30),14,16(29),17,19,21(26),22,24,27,31,35-octadecaene

Short Name benzovalene

Formula C36H16

Mass 448.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2013 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM