Heptacyclo[15.9.1.118,22.02,7.09,27.010,15.026,28]octacosa-1(27),2(7),3,8,10,12,14,16,18,20,22(28),23,25-tridecaene-5,6-dione (C28H14O2) - excitons of #2042

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.001 2.488 eV
S2 0.219 2.987 eV
S3 0.355 3.327 eV
S4 0.226 3.577 eV
S5 0.003 3.794 eV
S6 0.294 4.056 eV
S7 0.010 4.245 eV
S8 0.162 4.323 eV
S9 0.046 4.566 eV
S10 0.001 4.743 eV
S11 0.001 4.755 eV
S12 0.320 4.830 eV
S13 0.021 4.893 eV
S14 0.041 4.976 eV
S15 0.017 4.992 eV
S16 0.007 5.029 eV
S17 0.061 5.122 eV
S18 0.215 5.259 eV
S19 0.112 5.359 eV
S20 0.470 5.521 eV
S21 0.075 5.749 eV
S22 0.176 5.849 eV
S23 0.047 5.867 eV
S24 0.081 5.950 eV
S25 0.184 5.998 eV
S26 0.090 6.067 eV
S27 0.055 6.126 eV
S28 0.065 6.164 eV
S29 0.243 6.180 eV
S30 0.462 6.207 eV
S31 0.435 6.275 eV
S32 0.065 6.284 eV
S33 0.041 6.341 eV
S34 0.006 6.366 eV
S35 0.043 6.432 eV
S36 0.193 6.479 eV
S37 0.101 6.503 eV
S38 0.048 6.532 eV
S39 0.070 6.573 eV
S40 0.014 6.644 eV
S41 0.039 6.648 eV
S42 0.126 6.694 eV
S43 0.009 6.712 eV
S44 0.046 6.775 eV
S45 0.314 6.819 eV
S46 0.007 6.845 eV
S47 0.061 6.866 eV
S48 0.116 6.877 eV
S49 0.048 6.928 eV
S50 0.424 6.958 eV
S51 0.328 6.989 eV
S52 0.098 7.030 eV
S53 0.067 7.045 eV
S54 0.297 7.083 eV
S55 0.242 7.126 eV
S56 0.190 7.154 eV
S57 0.012 7.192 eV
S58 0.024 7.196 eV
S59 0.069 7.221 eV
S60 0.016 7.247 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -33344.99

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 09:00:18

Legacy ID None

System


Full Name Heptacyclo[15.9.1.118,22.02,7.09,27.010,15.026,28]octacosa-1(27),2(7),3,8,10,12,14,16,18,20,22(28),23,25-tridecaene-5,6-dione

Short Name dibenzperylen-chinon

Formula C28H14O2

Mass 382.4 u

Point Group C1

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2042 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM