8,9-Difluorohexacyclo[16.8.0.02,11.05,10.012,17.019,24]hexacosa-1(18),2(11),3,5(10),6,8,12,14,16,19,21,23,25-tridecaene (C26H14F2) - excitons of #2045

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.011 3.839 eV
S2 0.027 3.978 eV
S3 0.018 4.342 eV
S4 0.399 4.574 eV
S5 0.550 4.723 eV
S6 0.853 4.817 eV
S7 0.844 5.130 eV
S8 0.114 5.268 eV
S9 0.192 5.329 eV
S10 0.233 5.448 eV
S11 0.009 5.513 eV
S12 0.073 5.553 eV
S13 0.058 5.615 eV
S14 0.039 5.674 eV
S15 0.082 5.732 eV
S16 0.014 5.940 eV
S17 0.006 6.043 eV
S18 0.016 6.112 eV
S19 0.018 6.159 eV
S20 0.011 6.203 eV
S21 0.020 6.310 eV
S22 0.023 6.537 eV
S23 0.131 6.607 eV
S24 0.045 6.622 eV
S25 0.082 6.650 eV
S26 0.139 6.737 eV
S27 0.169 6.744 eV
S28 0.010 6.763 eV
S29 0.333 6.791 eV
S30 0.087 6.805 eV
S31 0.056 6.857 eV
S32 0.058 6.939 eV
S33 0.005 7.014 eV
S34 0.032 7.057 eV
S35 0.027 7.090 eV
S36 0.002 7.103 eV
S37 0.032 7.117 eV
S38 0.001 7.159 eV
S39 0.049 7.174 eV
S40 0.146 7.215 eV
S41 0.029 7.247 eV
S42 0.018 7.260 eV
S43 0.009 7.293 eV
S44 0.070 7.346 eV
S45 0.100 7.384 eV
S46 0.055 7.400 eV
S47 1.066 7.458 eV
S48 0.111 7.462 eV
S49 0.187 7.478 eV
S50 0.218 7.500 eV
S51 0.021 7.530 eV
S52 0.037 7.554 eV
S53 0.008 7.602 eV
S54 0.095 7.609 eV
S55 0.002 7.653 eV
S56 0.030 7.670 eV
S57 0.027 7.706 eV
S58 0.155 7.709 eV
S59 0.030 7.737 eV
S60 0.067 7.745 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -32611.48

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 09:01:23

Legacy ID None

System


Full Name 8,9-Difluorohexacyclo[16.8.0.02,11.05,10.012,17.019,24]hexacosa-1(18),2(11),3,5(10),6,8,12,14,16,19,21,23,25-tridecaene

Short Name difluorobenzo-[s]picene

Formula C26H14F2

Mass 364.4 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2045 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM