Nonacyclo[16.12.0.02,6.03,16.04,13.05,10.017,21.019,28.020,25]triaconta-1,3(16),4(13),5(10),6,8,11,14,17,19(28),20(25),21,23,26,29-pentadecaene (C30H14) - excitons of #2050

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 Bu 0.025 2.843 eV
S2 Bu 0.330 3.395 eV
S3 Ag 0.000 3.488 eV
S4 Bu 0.221 3.581 eV
S5 Ag 0.000 4.117 eV
S6 Bu 0.429 4.335 eV
S7 Ag 0.000 4.387 eV
S8 Bu 0.512 4.648 eV
S9 Ag 0.000 4.800 eV
S10 Bu 0.114 4.985 eV
S11 Ag 0.000 5.002 eV
S12 Ag 0.000 5.115 eV
S13 Bu 0.201 5.185 eV
S14 Ag 0.000 5.246 eV
S15 Bu 0.974 5.297 eV
S16 Ag 0.000 5.576 eV
S17 Bu 0.176 5.672 eV
S18 Ag 0.000 5.677 eV
S19 Ag 0.000 5.748 eV
S20 Au 0.000 5.822 eV
S21 Ag 0.000 5.875 eV
S22 Bu 0.469 5.881 eV
S23 Bu 0.036 5.911 eV
S24 Bg 0.000 6.032 eV
S25 Ag 0.000 6.094 eV
S26 Bu 0.868 6.132 eV
S27 Au 0.000 6.142 eV
S28 Bu 0.227 6.315 eV
S29 Bg 0.000 6.321 eV
S30 Bu 0.241 6.401 eV
S31 Ag 0.000 6.430 eV
S32 Bu 0.336 6.448 eV
S33 Ag 0.000 6.538 eV
S34 Bu 1.023 6.643 eV
S35 Bu 0.117 6.688 eV
S36 Au 0.000 6.695 eV
S37 Ag 0.000 6.702 eV
S38 Bu 0.457 6.723 eV
S39 Ag 0.000 6.764 eV
S40 Bu 0.249 6.773 eV
S41 Au 0.001 6.783 eV
S42 Ag 0.000 6.875 eV
S43 Bu 0.455 6.954 eV
S44 Au 0.002 7.067 eV
S45 Ag 0.000 7.075 eV
S46 Bu 0.132 7.084 eV
S47 Bg 0.000 7.103 eV
S48 Bg 0.000 7.132 eV
S49 Ag 0.000 7.190 eV
S50 Bu 0.028 7.225 eV
S51 Ag 0.000 7.251 eV
S52 Au 0.000 7.272 eV
S53 Bg 0.000 7.304 eV
S54 Bu 0.508 7.361 eV
S55 Ag 0.000 7.381 eV
S56 Bg 0.000 7.409 eV
S57 Au 0.002 7.411 eV
S58 Bu 0.315 7.420 eV
S59 Au 0.002 7.445 eV
S60 Bg 0.000 7.451 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31323.90

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 09:03:38

Legacy ID None

System


Full Name Nonacyclo[16.12.0.02,6.03,16.04,13.05,10.017,21.019,28.020,25]triaconta-1,3(16),4(13),5(10),6,8,11,14,17,19(28),20(25),21,23,26,29-pentadecaene

Short Name hepta[5][5]circulene

Formula C30H14

Mass 374.4 u

Point Group C2h

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2050 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM