Heptacyclo[20.8.0.02,11.03,8.012,21.013,18.025,30]triaconta-1,3,5,7,9,11,13,15,17,19,21,23,25,27,29-pentadecaene (C30H18) - excitons of #2054

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.004 3.676 eV
S2 0.016 3.885 eV
S3 0.545 4.329 eV
S4 0.002 4.384 eV
S5 0.029 4.444 eV
S6 0.833 4.529 eV
S7 0.063 4.823 eV
S8 0.284 4.879 eV
S9 0.005 4.951 eV
S10 0.128 5.122 eV
S11 1.116 5.206 eV
S12 0.109 5.266 eV
S13 0.250 5.303 eV
S14 0.119 5.408 eV
S15 0.053 5.436 eV
S16 0.068 5.586 eV
S17 0.014 5.766 eV
S18 0.030 5.854 eV
S19 0.042 5.893 eV
S20 0.024 5.959 eV
S21 0.034 6.043 eV
S22 0.016 6.114 eV
S23 0.175 6.193 eV
S24 0.067 6.239 eV
S25 0.107 6.246 eV
S26 0.042 6.298 eV
S27 0.013 6.355 eV
S28 0.042 6.360 eV
S29 0.027 6.418 eV
S30 0.778 6.529 eV
S31 0.241 6.578 eV
S32 0.296 6.602 eV
S33 0.052 6.678 eV
S34 0.088 6.685 eV
S35 0.043 6.736 eV
S36 0.250 6.741 eV
S37 0.055 6.750 eV
S38 0.097 6.821 eV
S39 0.175 6.833 eV
S40 0.120 6.841 eV
S41 0.003 6.927 eV
S42 0.234 6.961 eV
S43 0.043 6.974 eV
S44 0.044 7.045 eV
S45 0.012 7.054 eV
S46 0.107 7.086 eV
S47 0.036 7.102 eV
S48 0.002 7.136 eV
S49 0.016 7.145 eV
S50 0.078 7.153 eV
S51 0.030 7.170 eV
S52 0.011 7.206 eV
S53 0.003 7.246 eV
S54 0.039 7.270 eV
S55 0.069 7.288 eV
S56 0.039 7.309 eV
S57 0.006 7.313 eV
S58 0.020 7.332 eV
S59 0.012 7.350 eV
S60 0.031 7.366 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31389.51

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 09:05:47

Legacy ID None

System


Full Name Heptacyclo[20.8.0.02,11.03,8.012,21.013,18.025,30]triaconta-1,3,5,7,9,11,13,15,17,19,21,23,25,27,29-pentadecaene

Short Name naphtho[1,2-i]pentahelicene

Formula C30H18

Mass 378.5 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2054 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM