Heptacyclo[18.6.2.02,15.04,13.06,11.017,27.024,28]octacosa-1(27),2,4,6,8,10,12,14,16,18,20(28),21,23,25-tetradecaene (C28H16) - excitons of #2056

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.236 2.784 eV
S2 A' 0.001 3.409 eV
S3 A' 0.392 3.755 eV
S4 A' 0.064 4.014 eV
S5 A' 0.032 4.250 eV
S6 A' 2.366 4.550 eV
S7 A' 0.939 4.600 eV
S8 A' 0.226 4.807 eV
S9 A' 0.187 4.887 eV
S10 A' 0.124 4.924 eV
S11 A' 0.398 5.125 eV
S12 A' 0.005 5.391 eV
S13 A' 0.093 5.497 eV
S14 A' 0.423 5.591 eV
S15 A' 0.319 5.629 eV
S16 A' 0.008 5.632 eV
S17 A' 0.078 5.731 eV
S18 A' 0.003 5.843 eV
S19 A' 0.206 5.938 eV
S20 A" 0.000 6.034 eV
S21 A' 0.301 6.111 eV
S22 A" 0.000 6.156 eV
S23 A' 0.043 6.237 eV
S24 A' 0.084 6.283 eV
S25 A" 0.000 6.310 eV
S26 A' 0.038 6.353 eV
S27 A" 0.000 6.379 eV
S28 A" 0.000 6.395 eV
S29 A' 0.011 6.413 eV
S30 A' 0.028 6.450 eV
S31 A" 0.000 6.524 eV
S32 A' 0.005 6.558 eV
S33 A' 0.096 6.656 eV
S34 A" 0.000 6.684 eV
S35 A" 0.000 6.698 eV
S36 A' 0.035 6.740 eV
S37 A" 0.000 6.790 eV
S38 A' 0.002 6.814 eV
S39 A' 0.049 6.828 eV
S40 A" 0.000 6.856 eV
S41 A' 0.098 6.915 eV
S42 A' 0.023 6.946 eV
S43 A' 0.029 7.031 eV
S44 A" 0.000 7.061 eV
S45 A' 0.001 7.075 eV
S46 A" 0.001 7.079 eV
S47 A' 0.107 7.141 eV
S48 A' 0.071 7.204 eV
S49 A' 0.001 7.247 eV
S50 A" 0.000 7.265 eV
S51 A' 0.102 7.340 eV
S52 A" 0.000 7.349 eV
S53 A" 0.001 7.358 eV
S54 A' 0.012 7.404 eV
S55 A' 0.310 7.441 eV
S56 A" 0.000 7.462 eV
S57 A" 0.001 7.487 eV
S58 A" 0.000 7.490 eV
S59 A" 0.000 7.531 eV
S60 A' 0.040 7.532 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -29283.68

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 09:06:37

Legacy ID None

System


Full Name Heptacyclo[18.6.2.02,15.04,13.06,11.017,27.024,28]octacosa-1(27),2,4,6,8,10,12,14,16,18,20(28),21,23,25-tetradecaene

Short Name naphtho(2,1,8-uva)pentacene

Formula C28H16

Mass 352.4 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2056 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM