Octacyclo[15.13.1.122,26.02,15.05,14.06,11.021,31.030,32]dotriaconta-1(31),2(15),3,5(14),6(11),9,12,16,18,20,22,24,26(32),27,29-pentadecaene-7,8-dione (C32H16O2) - excitons of #2067

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.000 2.397 eV
S2 0.333 2.725 eV
S3 0.460 3.006 eV
S4 0.124 3.377 eV
S5 0.001 3.699 eV
S6 0.104 3.849 eV
S7 0.045 3.982 eV
S8 0.056 4.057 eV
S9 0.042 4.178 eV
S10 0.039 4.345 eV
S11 0.051 4.437 eV
S12 0.543 4.618 eV
S13 0.142 4.723 eV
S14 0.219 4.740 eV
S15 0.012 4.880 eV
S16 0.019 5.059 eV
S17 0.069 5.080 eV
S18 0.013 5.129 eV
S19 0.106 5.223 eV
S20 0.442 5.263 eV
S21 0.017 5.313 eV
S22 0.429 5.326 eV
S23 0.037 5.586 eV
S24 0.151 5.645 eV
S25 0.196 5.720 eV
S26 0.039 5.773 eV
S27 0.093 5.831 eV
S28 0.010 5.848 eV
S29 0.073 5.899 eV
S30 0.052 5.918 eV
S31 0.133 6.032 eV
S32 0.407 6.053 eV
S33 0.083 6.095 eV
S34 0.003 6.123 eV
S35 0.004 6.136 eV
S36 0.059 6.151 eV
S37 0.019 6.256 eV
S38 0.071 6.290 eV
S39 0.072 6.302 eV
S40 0.015 6.362 eV
S41 0.006 6.395 eV
S42 0.001 6.410 eV
S43 0.463 6.448 eV
S44 0.049 6.456 eV
S45 0.032 6.535 eV
S46 0.042 6.561 eV
S47 0.001 6.594 eV
S48 0.011 6.611 eV
S49 0.410 6.624 eV
S50 0.020 6.651 eV
S51 0.076 6.696 eV
S52 0.183 6.737 eV
S53 0.037 6.751 eV
S54 0.069 6.767 eV
S55 0.010 6.814 eV
S56 0.018 6.830 eV
S57 0.057 6.870 eV
S58 0.231 6.881 eV
S59 0.016 6.911 eV
S60 0.043 6.938 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -37524.88

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-14 09:12:15

Legacy ID None

System


Full Name Octacyclo[15.13.1.122,26.02,15.05,14.06,11.021,31.030,32]dotriaconta-1(31),2(15),3,5(14),6(11),9,12,16,18,20,22,24,26(32),27,29-pentadecaene-7,8-dione

Short Name phenanthroperylenequinone

Formula C32H16O2

Mass 432.5 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2067 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM