Nonacyclo[15.13.1.12,12.13,7.118,22.027,31.011,34.016,33.026,32]tetratriaconta-1,3,5,7(34),8,10,12(33),13,15,17(31),18,20,22(32),23,25,27,29-heptadecaene (C34H18) - excitons of #2078

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B 0.905 2.429 eV
S2 A 0.006 3.379 eV
S3 A 0.008 3.572 eV
S4 B 0.003 3.621 eV
S5 B 0.022 4.033 eV
S6 A 0.000 4.056 eV
S7 B 0.027 4.100 eV
S8 B 0.106 4.227 eV
S9 A 0.000 4.361 eV
S10 B 0.051 4.454 eV
S11 A 0.001 4.540 eV
S12 B 0.149 4.611 eV
S13 B 0.061 4.752 eV
S14 A 0.068 4.901 eV
S15 B 0.303 4.999 eV
S16 B 0.627 5.217 eV
S17 A 0.000 5.220 eV
S18 A 0.000 5.415 eV
S19 A 0.000 5.511 eV
S20 B 0.001 5.557 eV
S21 A 0.000 5.640 eV
S22 A 0.001 5.680 eV
S23 B 0.059 5.703 eV
S24 A 0.004 5.793 eV
S25 A 0.008 5.850 eV
S26 A 0.009 5.946 eV
S27 A 0.002 6.007 eV
S28 B 0.125 6.024 eV
S29 B 0.492 6.100 eV
S30 A 0.001 6.112 eV
S31 B 0.122 6.200 eV
S32 B 0.015 6.217 eV
S33 A 0.003 6.255 eV
S34 B 0.686 6.282 eV
S35 A 0.003 6.291 eV
S36 A 0.063 6.336 eV
S37 B 0.774 6.340 eV
S38 A 0.021 6.343 eV
S39 A 0.005 6.369 eV
S40 B 0.067 6.382 eV
S41 A 0.034 6.398 eV
S42 B 0.104 6.451 eV
S43 B 0.032 6.499 eV
S44 B 0.020 6.547 eV
S45 A 0.001 6.561 eV
S46 B 0.040 6.606 eV
S47 A 0.025 6.622 eV
S48 B 0.014 6.637 eV
S49 A 0.003 6.669 eV
S50 B 0.135 6.673 eV
S51 B 0.177 6.752 eV
S52 A 0.035 6.790 eV
S53 B 0.391 6.835 eV
S54 A 0.003 6.888 eV
S55 B 0.138 6.894 eV
S56 B 0.179 6.912 eV
S57 A 0.013 6.914 eV
S58 B 0.213 6.928 eV
S59 A 0.001 6.961 eV
S60 B 0.474 6.964 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -35537.36

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 09:53:12

Added 2026-09-14 09:18:22

Legacy ID None

System


Full Name Nonacyclo[15.13.1.12,12.13,7.118,22.027,31.011,34.016,33.026,32]tetratriaconta-1,3,5,7(34),8,10,12(33),13,15,17(31),18,20,22(32),23,25,27,29-heptadecaene

Short Name tetrabenzo(de,hi,op,st)pentacene

Formula C34H18

Mass 426.5 u

Point Group C2

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2078 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM