Nonacyclo[18.10.2.22,5.03,16.04,13.06,11.017,31.022,27.028,32]tetratriaconta-1(30),2(34),3(16),4(13),5(33),6,8,10,14,17(31),18,20(32),22,24,26,28-hexadecaene (C34H20) - excitons of #2091

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B2 1.257 2.895 eV
S2 B2 0.001 3.692 eV
S3 B2 0.005 3.955 eV
S4 A1 0.003 4.163 eV
S5 A1 0.014 4.230 eV
S6 B2 0.056 4.417 eV
S7 A1 0.003 4.440 eV
S8 B2 0.015 4.761 eV
S9 A1 0.013 4.784 eV
S10 B2 0.058 4.852 eV
S11 A1 0.064 5.149 eV
S12 A1 0.003 5.258 eV
S13 B2 0.066 5.381 eV
S14 A1 0.098 5.505 eV
S15 B2 0.005 5.530 eV
S16 B2 0.238 5.633 eV
S17 A1 0.060 5.699 eV
S18 A1 0.159 5.824 eV
S19 B2 0.089 5.851 eV
S20 A1 0.165 5.927 eV
S21 B2 0.044 5.929 eV
S22 B2 0.000 6.007 eV
S23 A1 0.039 6.015 eV
S24 A1 0.032 6.098 eV
S25 A2 0.000 6.106 eV
S26 A1 0.004 6.168 eV
S27 B1 0.001 6.169 eV
S28 A2 0.000 6.171 eV
S29 B2 1.962 6.192 eV
S30 B1 0.000 6.222 eV
S31 A2 0.000 6.224 eV
S32 B2 0.322 6.280 eV
S33 B2 0.445 6.369 eV
S34 B2 0.012 6.410 eV
S35 A1 0.009 6.446 eV
S36 B2 0.856 6.503 eV
S37 A2 0.000 6.509 eV
S38 A1 0.011 6.545 eV
S39 A1 0.019 6.593 eV
S40 B1 0.000 6.629 eV
S41 B2 0.000 6.687 eV
S42 B1 0.000 6.739 eV
S43 B2 0.044 6.831 eV
S44 A2 0.000 6.861 eV
S45 A2 0.000 6.898 eV
S46 A1 0.329 6.918 eV
S47 A1 0.069 6.969 eV
S48 B2 0.140 7.022 eV
S49 B1 0.002 7.035 eV
S50 A1 0.018 7.041 eV
S51 B2 0.018 7.041 eV
S52 A1 0.109 7.068 eV
S53 B2 0.016 7.113 eV
S54 A1 0.532 7.120 eV
S55 A2 0.000 7.127 eV
S56 B1 0.002 7.170 eV
S57 B2 0.005 7.231 eV
S58 A1 0.087 7.242 eV
S59 B2 0.000 7.275 eV
S60 A1 0.005 7.292 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -35570.32

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 09:55:47

Added 2026-09-14 09:25:03

Legacy ID None

System


Full Name Nonacyclo[18.10.2.22,5.03,16.04,13.06,11.017,31.022,27.028,32]tetratriaconta-1(30),2(34),3(16),4(13),5(33),6,8,10,14,17(31),18,20(32),22,24,26,28-hexadecaene

Short Name violanthrene

Formula C34H20

Mass 428.5 u

Point Group C2v

Orientation yz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2091 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM