7,19-Diphenyl-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2(11),3,5,7,9,14(23),15,17,19,21-undecaene (C34H20S2) - excitons of #2100

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B 0.697 3.544 eV
S2 B 0.509 4.009 eV
S3 A 0.000 4.086 eV
S4 A 0.000 4.183 eV
S5 B 2.797 4.652 eV
S6 B 0.000 4.717 eV
S7 A 0.000 4.774 eV
S8 B 1.019 5.017 eV
S9 A 0.000 5.144 eV
S10 B 0.016 5.234 eV
S11 A 0.000 5.237 eV
S12 A 0.000 5.252 eV
S13 B 0.337 5.430 eV
S14 B 0.031 5.437 eV
S15 A 0.000 5.451 eV
S16 B 0.388 5.499 eV
S17 A 0.000 5.687 eV
S18 B 0.086 5.805 eV
S19 A 0.001 5.807 eV
S20 B 0.000 5.857 eV
S21 A 0.001 5.873 eV
S22 A 0.002 5.907 eV
S23 B 0.286 5.926 eV
S24 B 0.011 5.988 eV
S25 A 0.019 5.994 eV
S26 B 0.225 6.081 eV
S27 A 0.001 6.089 eV
S28 A 0.000 6.136 eV
S29 A 0.001 6.288 eV
S30 B 0.386 6.292 eV
S31 A 0.006 6.316 eV
S32 B 0.197 6.324 eV
S33 B 0.095 6.368 eV
S34 A 0.001 6.372 eV
S35 B 0.060 6.397 eV
S36 B 0.023 6.485 eV
S37 B 0.367 6.515 eV
S38 A 0.000 6.613 eV
S39 B 0.104 6.641 eV
S40 A 0.001 6.642 eV
S41 A 0.001 6.728 eV
S42 B 0.027 6.740 eV
S43 A 0.004 6.762 eV
S44 A 0.006 6.827 eV
S45 B 0.159 6.830 eV
S46 B 0.239 6.839 eV
S47 A 0.003 6.849 eV
S48 B 0.015 6.864 eV
S49 A 0.006 6.875 eV
S50 B 0.006 6.900 eV
S51 A 0.006 6.903 eV
S52 B 0.353 6.938 eV
S53 A 0.003 6.950 eV
S54 B 0.135 6.951 eV
S55 A 0.031 6.979 eV
S56 B 0.000 6.995 eV
S57 A 0.000 7.004 eV
S58 A 0.000 7.046 eV
S59 B 0.001 7.052 eV
S60 B 0.002 7.063 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -57241.87

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 16:48:32

Added 2026-09-15 07:26:53

Legacy ID None

System


Full Name 7,19-Diphenyl-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2(11),3,5,7,9,14(23),15,17,19,21-undecaene

Short Name 29DPhDNTT

Formula C34H20S2

Mass 492.7 u

Point Group C2

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2100 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM