3,4,5,11,12,13-Hexafluoroundecacyclo[30.6.2.02,7.08,37.09,14.015,36.018,35.019,24.025,34.026,31.033,38]tetraconta-1(38),2,4,6,8(37),9,11,13,15(36),16,18(35),19,21,23,25(34),26,28,30,32,39-icosaene (C40H14F6) - excitons of #2121

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A 0.429 3.391 eV
S2 B 0.005 3.420 eV
S3 A 0.000 3.891 eV
S4 B 0.002 4.244 eV
S5 A 0.004 4.265 eV
S6 B 0.854 4.265 eV
S7 B 0.157 4.463 eV
S8 A 1.494 4.563 eV
S9 B 0.092 4.620 eV
S10 A 0.789 4.737 eV
S11 A 0.124 4.818 eV
S12 B 0.032 4.859 eV
S13 A 0.022 4.919 eV
S14 B 0.080 4.934 eV
S15 A 0.005 5.057 eV
S16 A 0.000 5.113 eV
S17 B 0.041 5.136 eV
S18 B 0.010 5.295 eV
S19 B 0.125 5.328 eV
S20 B 0.022 5.349 eV
S21 B 0.018 5.423 eV
S22 B 0.054 5.470 eV
S23 A 0.028 5.568 eV
S24 A 0.000 5.599 eV
S25 A 0.003 5.624 eV
S26 B 0.066 5.657 eV
S27 B 0.067 5.687 eV
S28 A 0.081 5.717 eV
S29 B 0.402 5.735 eV
S30 A 0.002 5.796 eV
S31 B 0.045 5.847 eV
S32 B 0.014 5.941 eV
S33 A 0.261 5.949 eV
S34 A 1.901 5.953 eV
S35 B 0.082 5.989 eV
S36 A 0.063 6.091 eV
S37 A 0.011 6.102 eV
S38 B 0.007 6.184 eV
S39 A 0.008 6.215 eV
S40 B 0.029 6.233 eV
S41 B 0.029 6.271 eV
S42 A 0.009 6.277 eV
S43 A 0.033 6.299 eV
S44 B 0.003 6.345 eV
S45 A 0.043 6.357 eV
S46 A 0.014 6.372 eV
S47 A 0.216 6.437 eV
S48 A 0.003 6.451 eV
S49 B 0.000 6.501 eV
S50 B 0.006 6.567 eV
S51 A 0.032 6.581 eV
S52 B 0.049 6.608 eV
S53 B 0.000 6.642 eV
S54 A 0.052 6.666 eV
S55 B 0.008 6.694 eV
S56 A 0.046 6.711 eV
S57 B 0.258 6.723 eV
S58 A 0.040 6.739 eV
S59 B 0.174 6.760 eV
S60 A 0.016 6.804 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -57997.98

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 05:41:54

Added 2026-09-15 07:43:29

Legacy ID None

System


Full Name 3,4,5,11,12,13-Hexafluoroundecacyclo[30.6.2.02,7.08,37.09,14.015,36.018,35.019,24.025,34.026,31.033,38]tetraconta-1(38),2,4,6,8(37),9,11,13,15(36),16,18(35),19,21,23,25(34),26,28,30,32,39-icosaene

Short Name CID102131291

Formula C40H14F6

Mass 608.5 u

Point Group C2

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2121 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM