5-Phenyl-14-[4-(trifluoromethyl)phenyl]pentacene (C35H21F3) - excitons of #2123

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.184 2.531 eV
S2 A' 0.000 3.502 eV
S3 A' 0.015 3.714 eV
S4 A' 0.001 3.926 eV
S5 A" 0.000 4.246 eV
S6 A' 0.218 4.494 eV
S7 A' 1.946 4.705 eV
S8 A' 0.688 4.773 eV
S9 A" 0.000 4.777 eV
S10 A' 0.252 4.798 eV
S11 A" 0.000 4.798 eV
S12 A' 1.611 4.969 eV
S13 A' 0.043 5.156 eV
S14 A" 0.000 5.189 eV
S15 A' 0.173 5.194 eV
S16 A' 0.017 5.468 eV
S17 A" 0.003 5.498 eV
S18 A' 0.007 5.513 eV
S19 A" 0.000 5.545 eV
S20 A' 0.019 5.555 eV
S21 A' 0.004 5.683 eV
S22 A' 0.034 5.743 eV
S23 A" 0.001 5.830 eV
S24 A' 0.006 5.917 eV
S25 A" 0.000 5.920 eV
S26 A' 0.002 5.952 eV
S27 A' 0.007 6.047 eV
S28 A" 0.000 6.059 eV
S29 A" 0.000 6.194 eV
S30 A' 0.254 6.200 eV
S31 A" 0.001 6.216 eV
S32 A' 0.441 6.252 eV
S33 A' 0.063 6.317 eV
S34 A" 0.000 6.318 eV
S35 A' 0.241 6.330 eV
S36 A" 0.000 6.332 eV
S37 A' 0.001 6.376 eV
S38 A" 0.000 6.428 eV
S39 A" 0.001 6.466 eV
S40 A' 0.001 6.485 eV
S41 A" 0.000 6.610 eV
S42 A" 0.001 6.633 eV
S43 A' 0.047 6.637 eV
S44 A' 0.001 6.673 eV
S45 A" 0.001 6.704 eV
S46 A" 0.001 6.712 eV
S47 A' 0.008 6.725 eV
S48 A" 0.000 6.800 eV
S49 A" 0.021 6.840 eV
S50 A' 0.000 6.878 eV
S51 A" 0.000 6.885 eV
S52 A' 0.009 6.906 eV
S53 A" 0.008 6.933 eV
S54 A' 0.017 6.959 eV
S55 A' 0.006 7.021 eV
S56 A" 0.006 7.051 eV
S57 A' 0.021 7.061 eV
S58 A" 0.008 7.070 eV
S59 A' 0.156 7.124 eV
S60 A" 0.057 7.164 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -44775.00

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 17:14:50

Added 2026-09-15 07:45:18

Legacy ID None

System


Full Name 5-Phenyl-14-[4-(trifluoromethyl)phenyl]pentacene

Short Name CID102261290

Formula C35H21F3

Mass 498.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2123 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM