7,18-Bis(5-chloro-2-methylphenyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone (C38H20Cl2N2O4) - excitons of #2131

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A" 1.260 2.956 eV
S2 A" 0.000 3.891 eV
S3 A' 0.000 4.015 eV
S4 A" 0.000 4.017 eV
S5 A" 0.000 4.129 eV
S6 A' 0.066 4.147 eV
S7 A' 0.000 4.162 eV
S8 A" 0.000 4.164 eV
S9 A" 0.000 4.397 eV
S10 A' 0.000 4.466 eV
S11 A' 0.000 4.561 eV
S12 A" 0.000 4.581 eV
S13 A' 0.000 4.602 eV
S14 A" 0.000 4.707 eV
S15 A' 0.000 4.721 eV
S16 A" 0.000 4.755 eV
S17 A' 0.011 5.001 eV
S18 A" 0.000 5.268 eV
S19 A" 0.034 5.335 eV
S20 A' 0.011 5.336 eV
S21 A' 0.443 5.629 eV
S22 A" 0.000 5.631 eV
S23 A' 0.013 5.786 eV
S24 A" 0.000 5.802 eV
S25 A' 0.000 5.807 eV
S26 A" 0.000 5.840 eV
S27 A' 0.000 5.847 eV
S28 A" 0.001 5.847 eV
S29 A' 0.000 5.906 eV
S30 A' 0.000 5.907 eV
S31 A' 0.019 5.996 eV
S32 A" 0.329 6.035 eV
S33 A' 0.003 6.089 eV
S34 A" 0.004 6.093 eV
S35 A" 0.002 6.095 eV
S36 A" 0.409 6.125 eV
S37 A" 0.000 6.154 eV
S38 A" 0.050 6.156 eV
S39 A' 0.176 6.157 eV
S40 A' 0.254 6.226 eV
S41 A' 0.002 6.309 eV
S42 A' 0.002 6.358 eV
S43 A" 0.000 6.359 eV
S44 A" 1.053 6.375 eV
S45 A' 0.000 6.423 eV
S46 A" 0.082 6.459 eV
S47 A" 2.030 6.475 eV
S48 A' 0.000 6.478 eV
S49 A" 0.027 6.487 eV
S50 A' 0.002 6.489 eV
S51 A" 0.019 6.506 eV
S52 A' 0.001 6.526 eV
S53 A' 0.001 6.535 eV
S54 A' 0.003 6.582 eV
S55 A" 0.015 6.589 eV
S56 A' 0.000 6.607 eV
S57 A' 0.000 6.663 eV
S58 A" 0.000 6.663 eV
S59 A' 0.116 6.671 eV
S60 A" 0.000 6.677 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -75935.34

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 11:09:18

Added 2026-09-15 07:52:36

Legacy ID None

System


Full Name 7,18-Bis(5-chloro-2-methylphenyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone

Short Name CID106682

Formula C38H20Cl2N2O4

Mass 639.5 u

Point Group Cs

Orientation zx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2131 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM