5,6,7,8,14,15-Hexafluoro-2,11,20,29,37,38,39,40-octazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene (C32H12F6N8) - excitons of #2157

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 0.680 2.255 eV
S2 A' 0.735 2.314 eV
S3 A' 0.063 3.633 eV
S4 A' 0.075 3.749 eV
S5 A' 0.034 4.051 eV
S6 A" 0.000 4.058 eV
S7 A" 0.000 4.110 eV
S8 A' 0.184 4.128 eV
S9 A' 0.001 4.208 eV
S10 A' 0.010 4.242 eV
S11 A' 0.250 4.292 eV
S12 A' 0.397 4.346 eV
S13 A' 0.086 4.365 eV
S14 A" 0.002 4.370 eV
S15 A' 0.159 4.430 eV
S16 A" 0.003 4.452 eV
S17 A' 0.094 4.477 eV
S18 A' 0.511 4.507 eV
S19 A' 0.015 4.516 eV
S20 A' 1.329 4.570 eV
S21 A" 0.000 4.594 eV
S22 A" 0.000 4.619 eV
S23 A' 0.084 4.622 eV
S24 A' 0.831 4.654 eV
S25 A" 0.001 4.696 eV
S26 A' 0.025 4.741 eV
S27 A' 0.057 4.757 eV
S28 A' 0.595 4.805 eV
S29 A' 0.070 4.841 eV
S30 A" 0.000 4.886 eV
S31 A' 0.210 4.958 eV
S32 A" 0.000 5.151 eV
S33 A' 0.338 5.192 eV
S34 A' 0.310 5.204 eV
S35 A" 0.000 5.252 eV
S36 A" 0.000 5.367 eV
S37 A" 0.000 5.436 eV
S38 A" 0.000 5.604 eV
S39 A' 0.030 5.643 eV
S40 A' 0.070 5.731 eV
S41 A' 0.028 5.821 eV
S42 A' 0.002 5.875 eV
S43 A' 0.004 6.034 eV
S44 A' 0.007 6.126 eV
S45 A' 0.077 6.221 eV
S46 A' 0.007 6.254 eV
S47 A" 0.000 6.307 eV
S48 A' 0.101 6.371 eV
S49 A' 0.051 6.401 eV
S50 A' 0.128 6.405 eV
S51 A" 0.000 6.435 eV
S52 A' 0.014 6.453 eV
S53 A' 0.224 6.569 eV
S54 A' 0.015 6.583 eV
S55 A' 0.015 6.599 eV
S56 A' 0.011 6.622 eV
S57 A" 0.000 6.631 eV
S58 A' 0.010 6.650 eV
S59 A" 0.000 6.660 eV
S60 A' 0.020 6.707 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -61588.43

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 06:51:16

Added 2026-09-15 08:17:50

Legacy ID None

System


Full Name 5,6,7,8,14,15-Hexafluoro-2,11,20,29,37,38,39,40-octazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene

Short Name CID135833479

Formula C32H12F6N8

Mass 622.5 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2157 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM